93001-00-4Relevant articles and documents
Rearrangements of the Isomeric Tolylmethylenes
Chapman, Orville L.,Johnson, Jeffery W.,Mahon, Robert J. Mc,West, Paul R.
, p. 501 - 509 (2007/10/02)
We present evidence for a mechanism in which the isomeric tolylmethylenes interconvert via methylcycloheptatetraene intermediates.Photolysis (>470 nm) of diazo compounds 1-4, matrix isolated in argon at 10 K, generates triplet tolylmethylenes 8-11.Photoly