930297-46-4

Basic information

• Product Name: [2,5-(phenyl-κC(2''),phenyl)]-1,3,4-oxadiazole-(κN1)(tetracarbonylmanganese(I))
• CAS NO: 930297-46-4
• Molecular Weight: 388.218
• Mol File: 930297-46-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [2,5-(phenyl-κC(2''),phenyl)]-1,3,4-oxadiazole-(κN1)(tetracarbonylmanganese(I))(CAS DataBase Reference)
• NIST Chemistry Reference: [2,5-(phenyl-κC(2''),phenyl)]-1,3,4-oxadiazole-(κN1)(tetracarbonylmanganese(I))(930297-46-4)
• EPA Substance Registry System: [2,5-(phenyl-κC(2''),phenyl)]-1,3,4-oxadiazole-(κN1)(tetracarbonylmanganese(I))(930297-46-4)

Safety Data

• Hazardous Substances Data: 930297-46-4(Hazardous Substances Data)

Upstream product

• 725-12-2 2,5-bis-(phenyl)-1,3,4-oxadiazole 

Downstream Products

• 930297-48-6 [1''2''2':η-2'-(diphenylmethylene)-phenyl]-5-phenyl-1,3,4-oxadiazole-(κN)-tricarbonylmanganese(I) 

Relevant articles and documents

Synthesis of cyclomanganated complexes derived from 2,5-diphenyl-1,3,4-oxadiazole and their reactivity with respect to 1,1-diphenyldiazomethane: Evidence for a fluxional trihaptobenzylic coordination mode

The cyclometallation of 2,5-diphenyl-1,3,4-oxadiazole with benzylpentacarbonylmanganese afforded the related mono- and binuclear complexes. The thermolytic coupling of 1,1-diphenyldiazomethane with monometallated 2,5-diphenyl-1,3,4-oxadiazole afforded substantial amounts of a new trihaptobenzylic complex. In the solid state, an X-ray diffraction analysis confirmed the coordination of manganese metal to one of the phenyl groups introduced by the 1,1-diphenyldiazomethane and to one of ligand's nitrogen centre. In solution, this trihaptobenzylic complex displays a fluxionality which is assumed to be related to the equilibration of its helical Λ and Δ enantiomers.