932395-39-6

Basic information

• Product Name: (Z)-(((3,3,3-trifluoroprop-1-en-1-yl)oxy)methyl)benzene
• Synonyms: (Z)-(((3,3,3-trifluoroprop-1-en-1-yl)oxy)methyl)benzene
• CAS NO: 932395-39-6
• Molecular Weight: 202.176
• Mol File: 932395-39-6.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (Z)-(((3,3,3-trifluoroprop-1-en-1-yl)oxy)methyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-(((3,3,3-trifluoroprop-1-en-1-yl)oxy)methyl)benzene(932395-39-6)
• EPA Substance Registry System: (Z)-(((3,3,3-trifluoroprop-1-en-1-yl)oxy)methyl)benzene(932395-39-6)

Safety Data

• Hazardous Substances Data: 932395-39-6(Hazardous Substances Data)

Upstream product

• 100-51-6 benzyl alcohol 
• 102687-65-0 trans-1-chloro-3,3,3-trifluoropropene 
• 99728-16-2 (Z)-1-chloro-3,3,3-trifluoro-1-propene 
• 2730-62-3 2-chloro-1,1,1-trifluoropropene 

Downstream Products

• 460-40-2 3,3,3-trifluoropropanal 
• 100-51-6 benzyl alcohol 
• 103-50-4 dibenzyl ether 

Relevant articles and documents

Applications of 2-Chloro-3,3,3-trifluoroprop-1-ene (HCFO-1233xf): A Rapid Entry to Various β-Substituted-trifluoromethyl-ethenes

An efficient base-promoted reaction of O-, N-, and S-nucleophiles with 2-chloro-3,3,3-trifluoprop-1-ene (HCFO-1233xf) is described providing access to various β-substituted-trifluoromethyl-ethenes under mild reaction conditions. Mechanistic investigations shed some light on the regio-, chemo-, and stereoselectivities observed. The olefins prepared represent attractive intermediates in chemical discovery: Some applications include their conversion to pyrrolidines via a [3 + 2] dipolar cycloaddition reaction. These weakly basic amines represent novel synthons that could be readily elaborated through a range of reactions.

METHOD FOR PRODUCING 3,3,3-TRIFLUOROPROPANOL

PROBLEM TO BE SOLVED: To provide a method for producing 3,3,3-trifluoropropanol efficiently on an industrial scale. SOLUTION: 3,3,3-trifluoropropanol is produced by the reaction between benzyl vinyl ether represented by the following formula [where R is a phenyl group, or a phenyl group having a substituent represented by R1 (where R1 is an alkyl group, an alkoxy group, a halogen atom or a nitro group)] and hydrogen (H2) in the presence of a palladium catalyst. SELECTED DRAWING: None COPYRIGHT: (C)2018,JPOandINPIT

PROCESS FOR PRODUCING 3,3,3-TRIFLUOROPROPIONALDEHYDE

A process for producing 3,3,3-trifluoropropionaldehyde which comprises hydrolyzing a benzyl vinyl ether represented by the formula [1]: (wherein R represents phenyl or phenyl substituted by R1 (R1 represents a member selected among alkyl, alkoxy, halogeno, and nitro)) in the presence of a catalyst selected among Arrhenius acids and Lewis acids.