933065-32-8Relevant articles and documents
Dynamic kinetic resolution of primary amines with a recyclable Pd nanocatalyst for racemization
Kim, Mahn-Joo,Kim, Won-Hee,Han, Kiwon,Yoon, Kyung Choi,Park, Jaiwook
, p. 1157 - 1159 (2007)
(Chemical Equation Presented) A practical procedure for the dynamic kinetic resolution (DKR) of primary amines has been developed. This procedure employs a palladium nanocatalyst as the racemization catalyst, a commercial lipase (Novozym-435) as the resol
Chemoenzymatic dynamic kinetic resolution of primary amines using a recyclable palladium nanoparticle catalyst together with lipases
Gustafson, Karl P. J.,Lihammar, Richard,Verho, Oscar,Engstroem, Karin,Baeckvall, Jan-E.
, p. 3747 - 3751 (2014/05/20)
A catalyst consisting of palladium nanoparticles supported on amino-functionalized siliceous mesocellular foam (Pd-AmP-MCF) was used in chemoenzymatic dynamic kinetic resolution (DKR) to convert primary amines to amides in high yields and excellent ee's.
Method for preparing optically active amines
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Page/Page column 15, (2009/09/29)
The present invention relates to a method of preparing optically active amines and chiral amines prepared thereby. The method includes reacting an amine compound, a metal catalyst, a biocatalyst including a lipase, and an acyl donor compound in an organic solvent to obtain a chiral amide compound, and then hydrolyzing the chiral amide compound to obtain a chiral amine.