93322-81-7

Basic information

• Product Name: Naphthalene, 2-methyl-1-(phenylthio)-
• CAS NO: 93322-81-7
• Molecular Formula: C17H14S
• Molecular Weight: 250.364
• Mol File: 93322-81-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Naphthalene, 2-methyl-1-(phenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: Naphthalene, 2-methyl-1-(phenylthio)-(93322-81-7)
• EPA Substance Registry System: Naphthalene, 2-methyl-1-(phenylthio)-(93322-81-7)

Safety Data

• Hazardous Substances Data: 93322-81-7(Hazardous Substances Data)

Upstream product

• 2586-62-1 1-bromo-2-methylnaphtalene 
• 1192-40-1 copper(I) thiophenolate 
• 108-98-5 thiophenol 
• 930-69-8 sodium thiophenolate 
• 68299-58-1 β-naphthylmethyl phenyl ether 

Downstream Products

• 51793-69-2 2-Benzyl-<1>naphthylsulfinsaeure 
• 94540-88-2 (2-Methyl-naphthyl-⁽¹⁾)-phenyl-sulfon 

Relevant articles and documents

Atropoisomerism in Hindered Naphthyl Sulfoxides: Structure, Stereodynamics, and Chiral Resolution

Barriers for the E,Z interconversion of atropisomers of 1-naphthyl sulfoxides (ArSOR) having a methyl group at position 2 of the naphthalene moiety were measured by variable-temperature NMR.Their values were found to cover the range 10.6-18.4 kcal molsup

Fragmentation of anion radicals with elimination of aryloxy groups

4-Vinylbenzyl phenyl ether, 4-phenylbenzyl phenyl ether, 1- and 2-naphthylmethyl phenyl ethers react with sodium thiophenolate under photochemical stimulation with replacement of the phenoxy group. The composition of reaction products and relation of reactivity to the structure of substrates is consistent with anion-radical mechanism. The corresponding methoxy and cyano derivatives do not undergo the reaction.