93398-03-9

Basic information

• Product Name: Benzenamine, N-butyl-2-methoxy-5-nitro-
• CAS NO: 93398-03-9
• Molecular Formula: C11H16N2O3
• Molecular Weight: 224.26
• Mol File: 93398-03-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzenamine, N-butyl-2-methoxy-5-nitro-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N-butyl-2-methoxy-5-nitro-(93398-03-9)
• EPA Substance Registry System: Benzenamine, N-butyl-2-methoxy-5-nitro-(93398-03-9)

Safety Data

• Hazardous Substances Data: 93398-03-9(Hazardous Substances Data)

Upstream product

• 455-93-6 2-fluoro-1-methoxy-4-nitrobenzene 
• 109-73-9 N-butylamine 
• 709-09-1 3,4-dimethoxynitrobenzene 

Relevant articles and documents

THE PHOTOREACTIONS OF 2-FLUORO-4-NITROANISOLE WITH AMINES. THE SEARCH FOR NEW BIOCHEMICAL PHOTOPROBES

The photosubstitutions of 2-fluoro-4-nitroanisole with several amines are studied from the preparative and the preliminary mechanistic points of view.The possible usefulness of this structure as biochemical photoprobe is discussed.

PHOTOREACTION OF 3,4-DIMETHOXY-1-NITROBENZENE WITH BUTYLAMINE. A pH DEPENDENCE OF REGIOSELECTIVITY

Irradiation of 3,4-dimethoxy-1-nitrobenzene in the presence of butylamine leads to the formation of both possible photosubstitution products, i.e., 2-methoxy-4-nitro-N-butylaniline and 2-methoxy-5-nitro-N-butylaniline with the predominance of the latter.Regioselectivity of the reaction as measured by molar ratio of the two isomeric products varies with pH of the solution, ranging from 3:1 at pH 10 to 12:1 at pH 12.The results are discussed in view of possible use of 3,4-dimethoxy-1-nitrobenzene moiety as a lysine-directed photoaffinity probe.