934559-80-5Relevant articles and documents
Functionalized N-heterocyclic carbene ligands for dual enantioselective control in the Cu-catalyzed conjugate addition of dialkylzinc compounds to acyclic enones
Dohi, Kenta,Kondo, Junko,Yamada, Haruka,Arakawa, Ryuichi,Sakaguchi, Satoshi
, p. 7143 - 7152 (2013/02/22)
A series of highly tunable, functionalized azolium compounds have been synthesized from chiral α-amino acid derivatives such as β-amino alcohols or α-amino esters. The combination of a Cu salt and a chiral azolium efficiently facilitated the asymmetric co
Hemilabile P-alkene ligands in chiral rhodium and copper complexes: Catalytic asymmetric 1,4 additions to enones. 2
Dorta, Romano,Drinkel, Emma,Briceno, Alexander,Dorta, Reto
experimental part, p. 2503 - 2514 (2010/08/04)
Two equivalents of the chiral dibenz[b,f]azepine-derived P-alkene ligands 2-6 per metal afforded mononuclear Rh(I) and Cu(I) complexes that were used as catalysts for asymmetric conjugate addition reactions. Rh formed square-planar neutral (8-10) and cati