93489-96-4

Basic information

• Product Name: (-)-menthyl (1R,5R)-2-methylenebicyclo<3.1.0>hexane-1-carboxylate
• Synonyms: (-)-menthyl (1R,5R)-2-methylenebicyclo<3.1.0>hexane-1-carboxylate
• CAS NO: 93489-96-4
• Molecular Weight: 276.419
• Mol File: 93489-96-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (-)-menthyl (1R,5R)-2-methylenebicyclo<3.1.0>hexane-1-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-menthyl (1R,5R)-2-methylenebicyclo<3.1.0>hexane-1-carboxylate(93489-96-4)
• EPA Substance Registry System: (-)-menthyl (1R,5R)-2-methylenebicyclo<3.1.0>hexane-1-carboxylate(93489-96-4)

Safety Data

• Hazardous Substances Data: 93489-96-4(Hazardous Substances Data)

Upstream product

• 74965-61-0 (1R,5R)-2-Oxo-bicyclo[3.1.0]hexane-1-carboxylic acid (1S,2R)-2-isopropyl-5-methyl-cyclohexyl ester 
• 1822-00-0 trimethylsilylmethyllithium 
• 74985-54-9 (-)-menthyl (1R,5R)-2-oxobicyclo<3.1.0>hexane-1-carboxylate 
• 111594-56-0 2-oxobicyclo<3.1.0>hexane-1-carboxylic acid 
• 61996-11-0 2-oxo-bicyclo[3.1.0]hexane-1-carboxylic acid methyl ester 
• 2216-51-5 (-)-menthol 
• 27200-84-6 methyl triphenylphosphonium bromide 

Downstream Products

• 101046-92-8 (1S)-1-methoxymethoxyvitamin D₃ 
• 101046-90-6 (-)-menthyl (1R,3S,5S)-3-methoxymethoxy-2-methylenebicyclo<3.1.0>hexane-1-carboxylate 
• 41294-56-8 1α-hydroxyvitamin D3 
• 101046-89-3 (1R,3S,5S)-3-Hydroxy-2-methylene-bicyclo[3.1.0]hexane-1-carboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester 
• 111594-57-1 (1R,5S)-2-Methylene-3-oxo-bicyclo[3.1.0]hexane-1-carboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester 
• 135447-02-8 (1R,3S,5S)-3-(tert-Butyl-dimethyl-silanyloxy)-2-methylene-bicyclo[3.1.0]hexane-1-carboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester 
• 32222-06-3 calcitriol 

Relevant articles and documents

Chiral ring A synthons for vitamin D synthesis

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A Stereoselective Synthesis of 1α-Hydroxyvitamin D3

A stereoslelective synthesis of 1α-hydroxyvitamin D3 (16) was achieved through the solvolysis of the 3,5-cyclovitamin D3 (14) which was prepared form (-)-(1R,3S,5S)-3-methoxymethoxy-2-methylenebicyclohexanecarbaldehyde (13) and 8-bromomethylenedes-AB-cholestane (1).