93493-97-1

Basic information

• Product Name: 1-Cyclohexene-1-carboxylic acid, 2-(trimethylstannyl)-, methyl ester
• CAS NO: 93493-97-1
• Molecular Formula: C11H20O2Sn
• Molecular Weight: 302.989
• Mol File: 93493-97-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-Cyclohexene-1-carboxylic acid, 2-(trimethylstannyl)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Cyclohexene-1-carboxylic acid, 2-(trimethylstannyl)-, methyl ester(93493-97-1)
• EPA Substance Registry System: 1-Cyclohexene-1-carboxylic acid, 2-(trimethylstannyl)-, methyl ester(93493-97-1)

Safety Data

• Hazardous Substances Data: 93493-97-1(Hazardous Substances Data)

Upstream product

• 93493-95-9 2-{[(trifluoromethyl)sulfonyl]oxy}cyclohex-1-enecarboxylic acid methyl ester 
• 122244-95-5 (CH₃)3SnC((CH₂)4Br)C(Sn(CH₃)3)(CO₂CH₃) 
• 917-54-4 methyllithium 

Downstream Products

• 93512-05-1 methyl 1-(3-chloropropyl)-2-(trimethylstannyl)-2-cyclohexenecarboxylate 

Relevant articles and documents

A new annulation method. Total syntheses of the sesquiterpenoids (+/-)-chiloscyphone and (+/-)-6-epi-chiloscyphone

The efficacy of a new annulation method, developed for the construction of functionalized bicyclic compounds, is illustrated by conversion of the β-keto esters 18 and 19 into the bicyclonon-1-enes 33 and 34, respectively, and by transformation of 2-methoxycarbonylcyclopentanone (20) into the bicyclonon-6-ene 38 and the bicyclodec-7-enes 48 and 51.Application of the method to total syntheses of the structurally unusual sesquiterpenoids (+/-)-chiloscyphone (16) and (+/-)-6-epi-chiloscyphone (17) is described.