935263-24-4

Basic information

• Product Name: (R)-(-)-N-(4-cyanobenzylidene)-2-methylpropane-2-sulfinamide
• Synonyms: (R)-(-)-N-(4-cyanobenzylidene)-2-methylpropane-2-sulfinamide
• CAS NO: 935263-24-4
• Molecular Weight: 234.322
• Mol File: 935263-24-4.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: (R)-(-)-N-(4-cyanobenzylidene)-2-methylpropane-2-sulfinamide(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-(-)-N-(4-cyanobenzylidene)-2-methylpropane-2-sulfinamide(935263-24-4)
• EPA Substance Registry System: (R)-(-)-N-(4-cyanobenzylidene)-2-methylpropane-2-sulfinamide(935263-24-4)

Safety Data

• Hazardous Substances Data: 935263-24-4(Hazardous Substances Data)

Upstream product

• 105-07-7 4-cyanobenzaldehyde 
• 196929-78-9 (R)-2-methylpropane-2-sulfinamide 

Downstream Products

• 1426955-77-2 (R_S,R)-N-(1-(4-cyanophenyl)-2-methylpropyl)-2-methylpropane-2-sulfinamide 
• 1426955-89-6 (R)-4-(1-amino-2-methylpropyl)benzonitrile hydrochloride 

Relevant articles and documents

HBF4·DEE-catalyzed formation of sulfinyl imines: Synthesis and mechanistic studies

A mild acid-catalysed method is reported for the formation of sulfinyl imines from tert-butanesulfinamide and aromatic or aliphatic aldehydes using tetrafluoroboric acid diethyletherate (10 mol%) in dichloromethane. Reactions were performed at room temper

AMIDE COMPOUNDS AND USE THEREOF

Disclosed are compounds of formula (I) below and pharmaceutically acceptable salts thereof, in which each of variables R1, R2, L, and Z is defined herein. Also disclosed are methods for reducing the glycemic level and treating glucag

Single or Synergistic Kinetic Resolutions of Chiral Allylalanes: Two Complementary Routes for the Asymmetric Synthesis of Syn Homoallylamines

Two strategies based on kinetic resolution(s) of chiral alanes and providing enantioenriched syn homoallylamines are reported. The first implies a single kinetic resolution of the alane using camphor; the second requires two sequential kinetic resolutions using the synergistic combination of (-)-camphor/(R)-tert-butylsulfinamide-derived imines. This syn selectivity, specific to the use of allyaluminum, opens the way to the preparation of valuable building blocks as illustrated by the synthesis of (+)-epilupinamine.