93532-41-3Relevant articles and documents
Rate and Equilibrium Constants of Dimethylcarbamoyl Transfer between Pyridine N-Oxides
Schroeder,Rybachenko,Chotii,Kovalenko,Grebenyuk,Lenska,Eitner
, p. 455 - 462 (2003)
Dimethylcarbamoyl transfer from N-acyloxypyridinium salts to pyridine N-oxides in acetonitrile occurs in one stage by the forced concerted SN2 mechanism. The rate and equilibrium of the reaction are fairly described by the Bronsted equation. The Marcus equation provides a much higher quality of reactivity predictions.