935554-58-8

Basic information

• Product Name: methyl 2,3,6-tri-O-benzyl-4-O-{3,4,6-tri-O-benzyl-2-O-[3'-(2''-benzyloxyphenyl)-3',3'-dimethylpropanoyl]-β-D-glucopyranosyl}-(1->4)-α-D-glucopyranoside
• Synonyms: methyl 2,3,6-tri-O-benzyl-4-O-{3,4,6-tri-O-benzyl-2-O-[3'-(2''-benzyloxyphenyl)-3',3'-dimethylpropanoyl]-β-D-glucopyranosyl}-(1->4)-α-D-glucopyranoside
• CAS NO: 935554-58-8
• Molecular Weight: 1163.41
• Mol File: 935554-58-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 2,3,6-tri-O-benzyl-4-O-{3,4,6-tri-O-benzyl-2-O-[3'-(2''-benzyloxyphenyl)-3',3'-dimethylpropanoyl]-β-D-glucopyranosyl}-(1->4)-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,3,6-tri-O-benzyl-4-O-{3,4,6-tri-O-benzyl-2-O-[3'-(2''-benzyloxyphenyl)-3',3'-dimethylpropanoyl]-β-D-glucopyranosyl}-(1->4)-α-D-glucopyranoside(935554-58-8)
• EPA Substance Registry System: methyl 2,3,6-tri-O-benzyl-4-O-{3,4,6-tri-O-benzyl-2-O-[3'-(2''-benzyloxyphenyl)-3',3'-dimethylpropanoyl]-β-D-glucopyranosyl}-(1->4)-α-D-glucopyranoside(935554-58-8)

Safety Data

• Hazardous Substances Data: 935554-58-8(Hazardous Substances Data)

Upstream product

• 129967-39-1 3-(2'-(Benzyloxy)phenyl)-3,3-dimethylpropionic Acid 
• 100-39-0 benzyl bromide 
• 29598-22-9 4,4-dimethyl-2-oxo-chroman 
• 935554-42-0 ethyl 3,4,6-tri-O-benzyl-2-O-[3'-(2''-benzyloxyphenyl)-3',3'-dimethylpropanoyl]-1-thio-β-D-glucopyranoside 
• 19488-48-3 methyl O-2,3,6-tri-O-benzyl-α-D-glucopyranoside 

Downstream Products

• 744-05-8 methyl 4-O-β-D-glucopyranosyl-(1->4)-α-D-glucopyranoside 

Relevant articles and documents

Stereocontrolled glycoside and glycosyl ester synthesis. Neighboring group participation and hydrogenolysis of 3-(2′-benzyloxyphenyl)-3,3- dimethylpropanoates

Equation presented The 2-O[3-(2′-benzyloxyphenyl)-3,3- dimethylpropanoate] and 2-O-[3-(2′-benzyloxy-4′,6′- dimethylphenyl)-3,3-dimethylpropanoate] esters enable the synthesis of a range of β-glucosides and α-mannosides through neighboring participation in excellent yield, and are removed by hydrogenolysis in concert with the cleavage of benzyl esters in the presence of other esters making them particularly well suited to the stereocontrolled synthesis of glycosyl esters.