936114-07-7

Basic information

• Product Name: methyl 5-nitro-2-[(5S)-5-{[(tert-butyl)dimethylsilyloxy]}-2-oxo-1-pyrrolidinyl]benzoate
• Synonyms: methyl 5-nitro-2-[(5S)-5-{[(tert-butyl)dimethylsilyloxy]}-2-oxo-1-pyrrolidinyl]benzoate
• CAS NO: 936114-07-7
• Molecular Weight: 408.527
• Mol File: 936114-07-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 5-nitro-2-[(5S)-5-{[(tert-butyl)dimethylsilyloxy]}-2-oxo-1-pyrrolidinyl]benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 5-nitro-2-[(5S)-5-{[(tert-butyl)dimethylsilyloxy]}-2-oxo-1-pyrrolidinyl]benzoate(936114-07-7)
• EPA Substance Registry System: methyl 5-nitro-2-[(5S)-5-{[(tert-butyl)dimethylsilyloxy]}-2-oxo-1-pyrrolidinyl]benzoate(936114-07-7)

Safety Data

• Hazardous Substances Data: 936114-07-7(Hazardous Substances Data)

Upstream product

• 6942-36-5 methyl 2-bromo-5-nitrobenzoate 
• 106191-02-0 (S)-5-((tert-butyldimethylsilyloxy)methyl)pyrrolidin-2-one 

Downstream Products

• 936114-23-7 methyl 5-amino-2-[(5S)-5-{[(tert-butyl)dimethylsilyiloxy]}-2-oxo-1-pyrrolidinyl]benzoate 

Relevant articles and documents

Total synthesis of (-)-martinellic acid

An enantioselective formal total synthesis of the pyrrolo[3,2-c]quinoline natural product martinellic acid has been achieved. The key steps involve a Pd-catalyzed aryl amidation reaction of a pyrroglutamate derivative, an intramolecular [3+2] azomethine ylide-alkene cycloaddition and a reductive ring opening reaction.