936574-32-2

Basic information

• Product Name: 4-formylphenyl (2,3,4,6-tetra-O-acetyl)-β-D-allopyranoside
• Synonyms: 4-formylphenyl (2,3,4,6-tetra-O-acetyl)-β-D-allopyranoside
• CAS NO: 936574-32-2
• Molecular Weight: 452.415
• Mol File: 936574-32-2.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: 4-formylphenyl (2,3,4,6-tetra-O-acetyl)-β-D-allopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: 4-formylphenyl (2,3,4,6-tetra-O-acetyl)-β-D-allopyranoside(936574-32-2)
• EPA Substance Registry System: 4-formylphenyl (2,3,4,6-tetra-O-acetyl)-β-D-allopyranoside(936574-32-2)

Safety Data

• Hazardous Substances Data: 936574-32-2(Hazardous Substances Data)

Upstream product

• 123-08-0 4-hydroxy-benzaldehyde 
• 4257-94-7 β-D-allose pentaacetate 
• 108-24-7 acetic anhydride 
• 80154-34-3 formaldehydephenlyl-O-β-D-pyranosyl alloside 

Downstream Products

• 1186032-08-5 5-[4-((2,3,4,6-tetra-O-acetyl)-β-D-allopyranosyloxy)benzylidene]-barbituric acid 
• 1186032-13-2 5-[4-((2,3,4,6-tetra-O-acetyl)-β-D-allopyranosyloxy)benzylidene]-2-thiobarbituric acid 
• 105054-56-6 4-(hydroxymethyl)phenyl 2,3,4,6-tetra-O-acetyl-β-D-allopyranoside 
• 80154-34-3 formaldehydephenlyl-O-β-D-pyranosyl alloside 
• 1234273-62-1 C₂₇H₃₂N₂O₁₂ 
• 1234273-63-2 C₂₇H₃₂N₂O₁₁S 
• 1234273-64-3 C₂₇H₃₂N₂O₁₃ 
• 1234273-65-4 C₂₇H₃₂N₂O₁₂S 

Relevant articles and documents

SLAP reagents for the photocatalytic synthesis of C3/C5-substituted, N-unprotected selenomorpholines and 1,4-selenazepanes

Herein, we disclose the first set of unique selenium-containing SLAP (SiLicon Amine Protocol) reagents for the direct synthesis of C3/C5-substituted selenomorpholines and 1,4-selenazepanes fromdiverse (hetero)aldehydes under mild photocatalytic conditions. Enantiomerically pure 1,2-amino alcohol/α-amino acid versions of these heterocycles were also synthesized. Further, we have shown the late-stage modification of certain biologically active agents using the developed seleno-SLAPreagents.

Preparation method of glucoside and derivatives thereof

The invention discloses a preparation method of glucoside and derivatives thereof. According to the method, all hydroxyl groups on a sugar molecule structure are acetylated, a ligand containing phenolic hydroxyl groups is prepared at the same time, then boron trifluoride-diethyl ether is used as a catalyst, the two substances are condensed to obtain tetraacetylated glucoside, and finally acetyl protecting groups are removed to obtain the required glucoside. The method can selectively catalyze hemiacetal hydroxyl of monosaccharide to react with hydroxyl to obtain glucoside, and the product is single. The method is simple in production operation and low in equipment requirement, can be used for synthesizing glucoside and derivatives thereof with similar structures, is green and environment-friendly, and can be used for large-scale production.

Helicid analogues for treating depression

The invention discloses helicid analogues for treating depression and relates to helicid derivatives such as 4-hydroxymethyl-beta-D-allopyranoside and 4-carboxylphenyl-beta-D-allopyranoside and their medicinal salts, esters and solvates. The helicid deriv