936737-82-5

Basic information

• Product Name: diethyl {[3-(4-nitrophenyl)prop-2-ynyloxy]methyl}phosphonate
• Synonyms: diethyl {[3-(4-nitrophenyl)prop-2-ynyloxy]methyl}phosphonate
• CAS NO: 936737-82-5
• Molecular Weight: 327.274
• Mol File: 936737-82-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: diethyl {[3-(4-nitrophenyl)prop-2-ynyloxy]methyl}phosphonate(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl {[3-(4-nitrophenyl)prop-2-ynyloxy]methyl}phosphonate(936737-82-5)
• EPA Substance Registry System: diethyl {[3-(4-nitrophenyl)prop-2-ynyloxy]methyl}phosphonate(936737-82-5)

Safety Data

• Hazardous Substances Data: 936737-82-5(Hazardous Substances Data)

Upstream product

• 18628-92-7 diethyl [(prop-2-ynyloxy)methyl]phosphonate 
• 586-78-7 para-nitrophenyl bromide 

Relevant articles and documents

ω-alkyne-mono- and diphosphonates - Synthesis and sonogashira cross-coupling reaction with aryl halides

A convergent approach to functionalise aromatic compounds with a linker terminated by a phosphonate group is reported. The starting point of this strategy is the synthesis of five new ω-alkyne-phosphonates. The linker between the phosphonate group and the alkyne part is either an alkyl or an ether chain. This strategy is based on the use of the phosphonate group as the anchoring point for the attachment of organic compounds onto alumina and the alkyne group, which is used to functionalise aryl halide compounds by a Sonogashira cross-coupling. The use of 1,10-phenanthroline as substrate illustrates the application of this strategy to an aromatic ligand. Wiley-VCH Verlag GmbH & Co. KGaA, 2007.