93728-41-7Relevant articles and documents
Copper-catalyzed regiodivergent 1,4-and 1,6-conjugate silyl addition to diendioates: Access to functionalized allylsilanes
Ahmad, Tanveer,Li, Qi,Qiu, Sheng-Qi,Xu, Jian-Lin,Xu, Yun-He,Loh, Teck-Peng
, p. 6122 - 6126 (2019)
A copper-catalyzed regioselective 1,4-and 1,6-conjugate addition of a silyl reagent to diendioates was established. Various 1,4-and 1,6-protosilylation products were obtained in good yields and with high regioselectivity via tuning the ligands used in the reactions. This protocol has provided a simple and efficient method for the synthesis of multisubstituted functionalized allylsilanes.