93845-81-9

Basic information

• Product Name: 2-Heptyn-1-one, 1-(4-methoxyphenyl)-
• CAS NO: 93845-81-9
• Molecular Formula: C14H16O2
• Molecular Weight: 216.28
• Mol File: 93845-81-9.mol
• Article Data: 41

Chemical Properties

• CAS DataBase Reference: 2-Heptyn-1-one, 1-(4-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Heptyn-1-one, 1-(4-methoxyphenyl)-(93845-81-9)
• EPA Substance Registry System: 2-Heptyn-1-one, 1-(4-methoxyphenyl)-(93845-81-9)

Safety Data

• Hazardous Substances Data: 93845-81-9(Hazardous Substances Data)

Upstream product

• 100-07-2 4-methoxy-benzoyl chloride 
• 693-02-7 hex-1-yne 
• 123-11-5 4-methoxy-benzaldehyde 
• 105-13-5 4-Methoxybenzyl alcohol 
• 3844-94-8 1-(trimethylsilyl)-1-hexyne 
• 201230-82-2 carbon monoxide 
• 696-62-8 para-iodoanisole 
• 1159987-54-8 tri(hexyn-1-yl)indium 
• 100-09-4 4-methoxybenzoic acid 
• 132353-25-4 2-(4-methoxybenzoyloxy)-4,6-dimethoxy-1,3,5-triazine 
• 18414-58-9 diphenylmethylsilanecarboxylic acid 
• 35864-20-1 1-hexynyltributyltin 
• 5720-07-0 4-methoxyphenylboronic acid 
• 115085-23-9 1-(4-methoxyphenyl)hept-2-yn-1-ol 

Downstream Products

• 1137261-90-5 1-(4-methoxyphenyl)-1,3-heptanedione 

Relevant articles and documents

Copper-catalyzed method for preparing aldehyde or ketone compound by oxidizing alcohol with oxygen as oxidizing agent and application

The invention discloses a copper-catalyzed method for preparing an aldehyde or ketone compound by oxidizing alcohol with oxygen as an oxidizing agent. Reaction is performed in an organic solvent for 4-48 hours at room temperature by using copper salt and nitroxide free radicals as catalysts and oxygen or air as an oxidizing agent to efficiently oxidize an alcohol compound into the corresponding aldehyde or ketone compound. The method is simple to operate, free of chlorides corrosive to equipment, available in raw materials and reagents, mild in reaction conditions, wide in substrate universality, good in functional group compatibility, convenient in separation and purification, environmentally friendly in the whole process and free of pollution, and is a method suitable for industrial production.

Copper-Catalyzed Aminoboration from Hydrazones to Generate Borylated Pyrazoles

Herein we report an aminoboration reaction that employs inexpensive, Earth-abundant, and commercially available Cu(OTf)2 as an effective catalyst in the direct addition of B-N σ bonds to C-C π bonds, generating borylated pyrazoles, which are us

Gem-Digold Acetylide Complexes for Catalytic Intermolecular [4 + 2] Cycloaddition: Having Two Gold Centers Is Better for Asymmetric Catalysis

Gold(I)-catalyzed highly enantioselective intermolecular [4 + 2] cycloaddition is shown with ynones and cyclohexadiene. Various bicyclo[2.2.2]octadiene derivatives are produced in high yields (up to 99%) with good enantioselectivity (up to 96% ee). Key to the success is generation of the gem-digold terminal alkyne as a catalytic on-cycle species. As proof of the gem-digold catalysis, a positive nonlinear effect is clarified between the ee's of the ligand and the cycloadduct.