93860-48-1Relevant articles and documents
Dehalogenation of hexachlorocyclohexanes and simultaneous chlorination of triethylsilane catalyzed by rhodium and ruthenium complexes
Esteruelas, Miguel A.,Herrero, Juana,Olivan, Montserrat
, p. 3891 - 3897 (2004)
Complexes RhCl(PPh3)3 and RhH2Cl(P iPr3)2 catalyze the dehalogenation of γ-hexachloro-cyclohexane to benzene and the simultaneous chlorination of HSiEt3 to ClSiEt3. In
Phosphinorhodium-catalyzed dehalogenation of chlorinated and fluorinated ethylenes: Distinct mechanisms with triethylsilane and dihydrogen
Peterson, Alicia A.,Thoreson, Kristen A.,McNeill, Kristopher
, p. 5982 - 5991 (2010/02/16)
Catalytic dehalogenation of chlorinated and fluorinated ethylenes by (PR3)3RhCl complexes is described. The C-Cl and C-F bonds are activated by the catalyst in the presence of triethylsilane (Et 3SiH) or dihydrogen (H