93867-72-2

Basic information

• Product Name: 7-(3-Methoxy-phenyl)-tropiliden
• Synonyms: 7-(3-Methoxy-phenyl)-tropiliden
• CAS NO: 93867-72-2
• Molecular Weight: 198.265
• Mol File: 93867-72-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 7-(3-Methoxy-phenyl)-tropiliden(CAS DataBase Reference)
• NIST Chemistry Reference: 7-(3-Methoxy-phenyl)-tropiliden(93867-72-2)
• EPA Substance Registry System: 7-(3-Methoxy-phenyl)-tropiliden(93867-72-2)

Safety Data

• Hazardous Substances Data: 93867-72-2(Hazardous Substances Data)

Upstream product

• 2398-37-0 3-methoxyphenyl bromide 
• 1714-38-1 7-methoxy-1,3,5-cycloheptatriene 
• 27081-10-3 tropylium tetrafluoroborate 
• 25230-72-2 tropylium perchlorate 

Downstream Products

• 209863-09-2 3'-methoxy-[1,1'-biphenyl]-4-carbaldehyde 
• 38491-36-0 3'-methoxy-[1,1′]-biphenyl-2-carbaldehyde 

Relevant articles and documents

Gold Catalysts Can Generate Nitrone Intermediates from a Nitrosoarene/Alkene Mixture, Enabling Two Distinct Catalytic Reactions: A Nitroso-Activated Cycloheptatriene/Benzylidene Rearrangement

Gold-catalyzed reactions of cycloheptatrienes with nitrosoarenes yield nitrone derivatives efficiently. This reaction sequence enables us to develop gold-catalyzed aerobic oxidations of cycloheptatrienes to afford benzaldehyde derivatives using CuCl and nitrosoarenes as co-catalysts (10-30 mol %). Our density functional theory calculations support a novel nitroso-activated rearrangement, tropylium → benzylidene. With the same nitrosoarenes, we developed their gold-catalyzed [2 + 2 + 1]-annulations between nitrosobenzene and two enol ethers to yield 5-alkoxyisoxazolidines using 1,4-cyclohexadienes as hydrogen donors.