939-28-6

Basic information

• Product Name: N-ethyl-N-(p-tolyl)nitrous amide
• Synonyms: N-ethyl-N-(p-tolyl)nitrous amide
• CAS NO: 939-28-6
• Molecular Weight: 164.207
• Mol File: 939-28-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-ethyl-N-(p-tolyl)nitrous amide(CAS DataBase Reference)
• NIST Chemistry Reference: N-ethyl-N-(p-tolyl)nitrous amide(939-28-6)
• EPA Substance Registry System: N-ethyl-N-(p-tolyl)nitrous amide(939-28-6)

Safety Data

• Hazardous Substances Data: 939-28-6(Hazardous Substances Data)

Upstream product

• 622-57-1 N-ethyl-p-tolylamine 
• 88876-21-5 N-allyl-N-ethyl-p-toluidine 
• 35113-87-2 N-ethyl-N-methyl-4-methylaniline 
• 106-49-0 p-toluidine 
• 135273-33-5 4-methyl-N-ethyl-N-benzylaniline 

Downstream Products

• 61715-72-8 N-ethyl-N-p-tolyl-hydrazine 
• 108843-59-0 3-nitro-benzaldehyde-(ethyl-p-tolyl-hydrazone) 

Relevant articles and documents

Highly selective sp3 C-N bond activation of tertiary anilines modulated by steric and thermodynamic factors

A highly selective sp3 C-N cleavage of tertiary anilines was achieved using the TBN/TEMPO catalyst system. When N,N-diaklylanilines (alkyl, benzyl) were employed, the N-CH3 bond was selectively cleaved via radical C-H activation. Moreover, when the allyl group was installed, totally reverse selectivity was observed. It is worth noting that the solvent effect is also crucial to obtain high reaction efficiency and selectivity.