93913-66-7

Basic information

• Product Name: 1α-Δ³-4,10α-dimethyl-7β-<2'β-(1'-benzyloxy)-propyl>-decalin
• CAS NO: 93913-66-7
• Molecular Weight: 312.495
• Mol File: 93913-66-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1α-Δ³-4,10α-dimethyl-7β-<2'β-(1'-benzyloxy)-propyl>-decalin(CAS DataBase Reference)
• NIST Chemistry Reference: 1α-Δ³-4,10α-dimethyl-7β-<2'β-(1'-benzyloxy)-propyl>-decalin(93913-66-7)
• EPA Substance Registry System: 1α-Δ³-4,10α-dimethyl-7β-<2'β-(1'-benzyloxy)-propyl>-decalin(93913-66-7)

Safety Data

• Hazardous Substances Data: 93913-66-7(Hazardous Substances Data)

Upstream product

• 93913-63-4 1α-Δ⁵-10α-methyl-7β-<2'β-(1'-benzyloxy)-propyl>-decalone-4 
• 93913-62-3 3(R)-methyl-6(S)-<1(R)-methyl-2-(phenylmethoxy)ethyl>-2(S)-(3-oxobutyl)cyclohexanone 
• 84051-31-0 (1R,5R)-2-(2-Benzyloxy-1-methyl-ethyl)-5-methyl-cyclohexanol 
• 13834-07-6 (1R,5R)-2-(2-Hydroxy-1-methyl-ethyl)-5-methyl-cyclohexanol 
• 100-44-7 benzyl chloride 
• 84051-32-1 (2S,5R)-2-((R)-1-(benzyloxy)propan-2-yl)-5-methylcyclohexanone 

Relevant articles and documents

TOTAL SYNTHESIS OF ARTEANNUIN AND DEOXYARTEANNUIN

Arteannuin 1 is a new sesquiterpene lactone containing a peroxide linkage and is an antimalarial principle isolated from Artemisia annua L. .R(+)-Citronellal 5 as a starting material for the total synthesis was converted into 11R(-)-methyl dihydroarteannuinate 12 in 14 steps.The key intermediate 4 was obtained from compound 12 in 5 steps.The introduction of hydroperoxide in 4 by photooxidation followed by acid treatment gave 1.Hydroxylation of 4 with osmium tetraoxide afforded deoxyarteannuin 2.