94162-44-4

Basic information

• Product Name: 3-Penten-2-ol, 4-methyl-1-(phenylmethoxy)-
• CAS NO: 94162-44-4
• Molecular Formula: C13H18O2
• Molecular Weight: 206.285
• Mol File: 94162-44-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3-Penten-2-ol, 4-methyl-1-(phenylmethoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Penten-2-ol, 4-methyl-1-(phenylmethoxy)-(94162-44-4)
• EPA Substance Registry System: 3-Penten-2-ol, 4-methyl-1-(phenylmethoxy)-(94162-44-4)

Safety Data

• Hazardous Substances Data: 94162-44-4(Hazardous Substances Data)

Upstream product

• 107-86-8 3,3-dimethyl acrylaldehyde 
• 71316-95-5 benzyloxymethyl lithium 
• 3017-69-4 2-methyl-1-propenylbromide 
• 60656-87-3 benzyloxyacetoaldehyde 

Downstream Products

• 83004-73-3 N-((E)-5-Benzyloxy-2,2-dimethyl-pent-3-enyl)-3-[1,3]dioxan-2-yl-propionamide 
• 94202-33-2 (R)-2-Acetoxy-N-((E)-5-benzyloxy-2,2-dimethyl-pent-3-enyl)-succinamic acid 
• 94162-50-2 (R)-3-Acetoxy-N-((E)-5-benzyloxy-2,2-dimethyl-pent-3-enyl)-succinamic acid 
• 86534-22-7 (+)-4(R)-acetoxy-1-<5-(benzyloxy)-2,2-dimethylpent-3-(E)-en-1-yl>-2,5-pyrrolidinedione 
• 86545-49-5 4(R)-acetoxy-1-<5-(benzyloxy)-2,2-dimethylpent-3(E)-en-1yl>-5-hydroxy-2-pyrrolidinone 
• 94162-49-9 tert-butyl N-<5-(benzyloxy)-2,2-dimethylpent-3(E)-en-1-yl>urethane 
• 86534-21-6 5-(benzyloxy)-2,2-dimethylpent-3(E)-enamine 
• 94162-47-7 (E)-6-Benzyloxy-3,3-dimethyl-hex-4-enoyl azide 
• 94162-48-8 ((E)-5-Isocyanato-4,4-dimethyl-pent-2-enyloxymethyl)-benzene 
• 86534-20-5 6-(benzyloxy)-3,3-dimethyl-4-hexenoyl chloride 
• 94162-45-5 (E)-6-(benzyloxy)-3,3-dimethyl-4-hexenoic acid 
• 160509-06-8 4-Methyl-1-(phenylmethoxy)-3-penten-2-yl 3-oxobutanoate 
• 94162-46-6 (E)-6-Benzyloxy-3,3-dimethyl-hex-4-enoic acid ethyl ester 

Relevant articles and documents

Intramolecular C-H insertion by an alkylidene carbene: Diastereoselective synthesis of a taxol A ring synthon

The first stage in a proposed total synthesis of the clinically effective anticancer agent taxol 1 is reported. A key step in this synthesis is the development of a new procedure for the generation and cyclization of the alkylidene carbene derived from ketone 9, to give cyclopentene 16 (formation of three new carbon-carbon bonds) in 72% yield. Ozonolysis of 16 followed by aldol condensation furnished the crystalline cyclohexenone 4.

REARRANGEMENTS OF N-ACYL-2-AZA-1,5-HEXADIENES: APPLICATION TO SYNTHESES OF TRAECHELANTHAMIDINE AND SUPINIDINE

Efficient syntheses of the pyrrolizidine bases traechelanthamidine (4) and supinidine (5) via an N-acyliminium ion rearrangement-cyclization are described.