94207-51-9Relevant articles and documents
A general Br?nsted acid-catalyzed allylation of benzhydryl alcohols
Orizu, Ifedi,Bolshan, Yuri
supporting information, p. 5798 - 5800 (2016/12/03)
Efficient Br?nsted acid-catalyzed allylation of benzhydryl alcohols has been developed. The reaction occurs within 5?min in the presence of sub-stoichiometric amounts of HBF4·OEt2to afford the desired products in good to excellent yields. A variety of functional groups were tolerated under the developed conditions including amides, aldehydes, hydroxyl and carboxylic acid.
Synergistic stereoselective organocatalysis with indium(III) salts
Gualandi, Andrea,Mengozzi, Luca,Wilson, Claire Margaret,Cozzi, Pier Giorgio
supporting information, p. 1321 - 1328 (2014/06/09)
The compatibility of indium(III) Lewis acids with water and amines allows their employment in synergistic and cooperative catalysis. Stereoselective organocatalytic SN1-type reactions, in which carbenium ions are generated, are promoted by the presence of indium salts. The peculiar properties of indium salts can be exploited in organocatalysis for the design of water-compatible, benign, green processes. The development of such indium(III)-promoted organocatalytic procedures is the focus of our recent research, a summary of which is presented in this article. Georg Thieme Verlag Stuttgart.New York.
