94348-71-7

Basic information

• Product Name: 2-Cyclohexen-1-one, 2-(hydroxyphenylmethyl)-
• CAS NO: 94348-71-7
• Molecular Formula: C13H14O2
• Molecular Weight: 202.253
• Mol File: 94348-71-7.mol
• Article Data: 36

Chemical Properties

• CAS DataBase Reference: 2-Cyclohexen-1-one, 2-(hydroxyphenylmethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclohexen-1-one, 2-(hydroxyphenylmethyl)-(94348-71-7)
• EPA Substance Registry System: 2-Cyclohexen-1-one, 2-(hydroxyphenylmethyl)-(94348-71-7)

Safety Data

• Hazardous Substances Data: 94348-71-7(Hazardous Substances Data)

Upstream product

• 930-68-7 cyclohexenone 
• 100-52-7 benzaldehyde 
• 937-14-4 3-chloro-benzenecarboperoxoic acid 

Downstream Products

• 1156004-31-7 2-[(p-toluidino)(phenyl)methyl]cyclohex-2-enone 
• 1156004-30-6 2-[(phenylamino)(phenyl)methyl]cyclohex-2-enone 
• 1156004-32-8 2-[(4-fluorophenylamino)(phenyl)methyl]cyclohex-2-enone 
• 1198078-54-4 2-(benzyloxy(phenyl)methyl)cyclohex-2-enone 
• 1198078-56-6 2-((ethylthio)(phenyl)methyl)cyclohex-2-enone 
• 1198078-42-0 2-((6-oxocyclohex-1-enyl)(phenyl)methyl)-1-phenylbutane-1,3-dione 
• 1198078-41-9 3-((6-oxocyclohex-1-enyl)(phenyl)methyl)-pentane-2,4-dione 
• 1198078-57-7 2-((4-chlorophenylthio)(phenyl)methyl)cyclohex-2-enone 
• 1198078-58-8 2-(phenyl(p-tolylthio)methyl)cyclohex-2-enone 
• 1198078-39-5 2-((6-oxocyclohex-1-enyl)(phenyl)methyl)-1,3-diphenylpropane-1,3-dione 
• 1198078-53-3 2-((4-hydroxy-3-methylphenyl)(phenyl)methyl)cyclohex-2-enone 
• 1198078-43-1 ethyl 2-benzoyl-3-(6-oxocyclohex-1-enyl)-3-phenylpropanoate 
• 133381-91-6 2-(ethoxy(phenyl)methyl)cyclohex-2-enone 
• 1198078-55-5 2-((but-3-enyloxy)(phenyl)methyl)cyclohex-2-enone 

Relevant articles and documents

Rhodium(II)-Catalyzed Reaction of 1-Tosyl-1,2,3-triazoles with Morita–Baylis–Hillman Adducts: Synthesis of 3,4-Fused Pyrroles

A cascade reaction of rhodium azavinylcarbenes with Morita–Baylis–Hillman (MBH) adducts enables a novel synthetic approach to 3,4-fused pyrroles. The cascade reaction begins with the insertion of O?H bond into rhodium azavinylcarbenes, subsquent sigmatropic rearrangement provides substituted α,β-unsaturated cyclic ketone intermediates. Then the intramolecular aza Michael addition/oxidative aromatization sequence give rise to a wide range of 3,4-fused pyrroles in good yields, and with excellent functional group compatibility.

Substituted (E)-2-methylene-3,4-cyclohexenones through direct and convenient synthesis from cyclohexenone-MBH alcohol in the presence of DMAP

An unexpected and effective DMAP catalyzed one-step construction of 3,4-cyclohexenone skeleton from simple and easily available cyclohexenone-MBH alcohol has been disclosed. A series of substituted (E)-2-methylene-3,4-cyclo-hexenones have been effectively prepared in excellent yields (up to 93 %) under convenient reaction conditions. Succesful scale-up preparation and synthetic transformations have demonstrated the potentials of this new protocol.

Efficient catalysis of aqueous Morita-Baylis-Hillman reactions of cyclic enones by a bicyclic imidazolyl alcohol

In this paper a new phosphorus-free catalyst for the Morita-Baylis-Hillman reaction is disclosed. A bicyclic imidazolyl alcohol having a Lewis basic center associated with a hydrogen-bond donor group was used as catalyst for the reaction. Aliphatic cycloalkanones such as 2-cyclopentenone and 2-cyclohexanone and aliphatic and aromatic aldehydes were used successfully, and the reaction was found to work nicely using water as solvent in the presence of a phase-transfer additive. Copyright