94372-07-3

Basic information

• Product Name: 3-Heptene, 2,2-dimethyl-, (Z)-
• CAS NO: 94372-07-3
• Molecular Formula: C9H18
• Molecular Weight: 126.242
• Mol File: 94372-07-3.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 3-Heptene, 2,2-dimethyl-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Heptene, 2,2-dimethyl-, (Z)-(94372-07-3)
• EPA Substance Registry System: 3-Heptene, 2,2-dimethyl-, (Z)-(94372-07-3)

Safety Data

• Hazardous Substances Data: 94372-07-3(Hazardous Substances Data)

Upstream product

• 2443-89-2 1,1-Diiodo-2,2-dimethylpropane 
• 123-72-8 butyraldehyde 
• 3739-96-6 (2,2-Dimethyl-propylidene)-triphenyl-λ⁵-phosphane 
• 94404-12-3 cis-P,P,P-tributyl-3-tert-butyl-4-propyloxaphosphetane 
• 3728-50-5 butylidenetriphenylphosphorane 
• 630-19-3 pivalaldehyde 
• 43216-19-9 Tributylbutylidenphosphoran 
• 128399-08-6 Butylidene-tris-(2-methoxymethoxy-phenyl)-λ⁵-phosphane 
• 62946-91-2 1-bromo-4,4-dimethyl-2-pentene 
• 925-90-6 ethylmagnesium bromide 
• 630-17-1 2,2-dimethylpropyl bromide 
• 917-54-4 methyllithium 
• 88106-32-5 1-bromo-1-cyclopropyl-2,2-dimethylpropane 
• 95979-33-2 neopentyl triphenylphosphonium bromide 

Relevant articles and documents

Copper-free asymmetric allylic alkylation with grignard reagents

(Chemical Equation Presented) Open wide and say AAA: The copper-free asymmetric allylic alkylation reaction of Crignard reagents, catalyzed by N-heter-ocyclic carbenes, is reported for allyl bromide derivatives. This reaction offers good enantioselectivit

Untersuchungen im Wittig-System nach einem ordnenden Konzept auf der Basis alternativer Prinzipien

Our results show that the stereoselectivity of the Wittig-reaction can be controlled by the variation of substituents in accord with the ORDERING CONCEPT OF ALTERNATIV PRINCIPLES (individual pairs, known and unknown classes of alternatives).The "all-phenyl Wittig-system" having three phenyl groups on phosphorous two in ylid- and aldehyd-position was chosen as a standard for our investigations.Differentiation in ylid-position and compensation on phosphorous and aldehyd-position were observed by the comparison of "patterns".Consequently, most of the selectivity rules of Wittig-reactions can be explained by the differentiation through alternatives in the ylid-position.Inversion or conservation of the "patterns" of measured data points to the variation in structure of starting materials, reaction rates and selectivities.Amount-controls were also described in certain systems.

(E)-Selective Olefination of Aldehydes by means of gem-Dichromium Reagents Derived by Reduction of gem-Diiodoalkanes with ChHromium(II) Chloride

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