943897-30-1

Basic information

• Product Name: {4-[(E)-3-hydroxy-3-methyl-1-butenyl]phenyl}(phenyl)methanone
• Synonyms: {4-[(E)-3-hydroxy-3-methyl-1-butenyl]phenyl}(phenyl)methanone
• CAS NO: 943897-30-1
• Molecular Weight: 266.34
• Mol File: 943897-30-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: {4-[(E)-3-hydroxy-3-methyl-1-butenyl]phenyl}(phenyl)methanone(CAS DataBase Reference)
• NIST Chemistry Reference: {4-[(E)-3-hydroxy-3-methyl-1-butenyl]phenyl}(phenyl)methanone(943897-30-1)
• EPA Substance Registry System: {4-[(E)-3-hydroxy-3-methyl-1-butenyl]phenyl}(phenyl)methanone(943897-30-1)

Safety Data

• Hazardous Substances Data: 943897-30-1(Hazardous Substances Data)

Upstream product

• 115-18-4 2-methyl-3-buten-2-ol 
• 90-90-4 (4-bromophenyl)(phenyl)methanone 

Relevant articles and documents

Heck reactions of aryl bromides with alk-1-en-3-ol derivatives catalysed by a tetraphosphine/palladium complex

cis,cis,cis-1,2,3,4-Tetrakis(diphenylphosphinomethyl)cyclopentane/ [PdCl(C3H5)]2 efficiently catalyses the Heck reaction of alk-1-en-3-ol with a variety of aryl bromides. In the presence of hex-1-en-3-ol or oct-1-en-3-ol, the β-arylated carbonyl compounds were selectively obtained. Linalool and 2-methylbut-3-en-2-ol led to the corresponding 1-arylalk-1-en-3-ol derivatives. Turnover numbers up to 69,000 can be obtained for this reaction. A minor electronic effect of the substituents of the aryl bromide was observed. Similar reaction rates were observed in the presence of activated aryl bromides such as bromoacetophenone and deactivated aryl bromides such as bromoanisole.