944284-25-7

Basic information

• Product Name: (1,3-bis(diphenylphosphino)propane)bis(1-pentenyl)platinum(II)
• Synonyms: (1,3-bis(diphenylphosphino)propane)bis(1-pentenyl)platinum(II)
• CAS NO: 944284-25-7
• Molecular Weight: 745.784
• Mol File: 944284-25-7.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: (1,3-bis(diphenylphosphino)propane)bis(1-pentenyl)platinum(II)(CAS DataBase Reference)
• NIST Chemistry Reference: (1,3-bis(diphenylphosphino)propane)bis(1-pentenyl)platinum(II)(944284-25-7)
• EPA Substance Registry System: (1,3-bis(diphenylphosphino)propane)bis(1-pentenyl)platinum(II)(944284-25-7)

Safety Data

• Hazardous Substances Data: 944284-25-7(Hazardous Substances Data)

Upstream product

• 12080-32-9 dichloro( 1,5-cyclooctadiene)platinum(ll) 
• 6737-42-4 1,3-bis-(diphenylphosphino)propane 
• 34164-50-6 4-penten-1-ylmagnesium bromide 
• 59329-00-9 [1,3-bis(diphenylphosphino)propane]dichloroplatinum(II) 
• 56039-93-1 3-butenylmagnesium chloride 

Downstream Products

• 959403-61-3 (CH₃)4C₅HIrC₅H₉⁽¹⁺⁾*Cl^(1-)=[(CH₃)4C₅HIrC₅H₉]Cl 
• 1008519-07-0 (η(3)-dimethylallyl)[1,3-bis(diphenylphosphino)propane]platinum(II) chloride 
• 1034739-61-1 Pt((CH₂)3CHCH₂)Cl(P₂(C₆H₅)4(CH₂)3) 
• 59329-02-1 [PtMe(I)(1,3-bis(diphenylphosphino)propane)] 
• 74429-98-4 cis-diiodo[1,1'-(propane-1,3-diyl)bis[1,1-diphenylphosphine-κP]]platinum 
• 59329-00-9 [1,3-bis(diphenylphosphino)propane]dichloroplatinum(II) 
• 1034739-62-2 [platinum(II)(1,3-bis(diphenylphosphino)propane)((CH₂)3CHCH₂)((CH₂)2CHCH₂)] 
• 1034739-64-4 [platinum(II)(1,3-bis(diphenylphosphino)propane)(CH₂)7] 
• 944284-36-0 [platinum(II)(1,3-bis(diphenylphosphino)propane)(CH₂)8] 
• 959934-91-9 cis-[Pt(2-pentenyl)2(1,3-bis(diphenylphosphino)propane)] 

Relevant articles and documents

Studies on reactivity of platinum-based heterobimetallic carbonyl clusters

Reactivity of platinum-based trinuclear carbonyl clusters of the type L2PtRu2(CO)8, where L2 = 1,3-bis(diphenylphosphino)propane (dppp) and 1,2-bis(diphenylphosphino)ethane (dppe), is described. Oxidative additi

Novel reactivity aspects of cis-bis(1-alkenyl)platinum(II) compounds of the type Pt(CH2(CH2)nCHCH2) 2L2 (where L2 = dppp, dppe, dppm and n = 1, 2)

We describe the synthesis, structure and reactivity of novel bis(1-alkenyl)platinum(II) complexes, Pt[CH2(CH2) nCHCH2]2L2 (where L2 = dppp, dppe, dppm and n = 1, 2). The stability of the title complexes with the different ligands is discussed. The steric, chelating and electronic properties of the ligands have a significant impact on the structure as well as on the reactivity of the complexes. Novel reactions with elemental sulfur and carbon dioxide are described and discussed.

Selective isomerization of cis-PtL2(1-alkenyl)2 to cis-PtL2(2-alkenyl)2 complexes

Heating the 1-alkenyl complexes cis-[Pt(1-alkenyl)2L 2] [alkenyl = 1-pentenyl, 1-hexenyl, 1-heptenyl, and 1-octenyl; L2 = 1,3-bis(diphenylphosphino)propane (dppp) or 1,2- bis(diphenylphosphino)ethane (dppe)] to 100°C caused a quantitative isomerization to the corresponding 2-alkenyl complexes cis-[Pt-(2-alkenyl) 2L2]. This novel isomerization is strongly dependent on the length of the alkenyl chains as well as the nature of the ligand, L 2. The new 2-alkenyl complexes were fully characterized by analytical and spectroscopic methods. An X-ray crystal structure of cis-[Pt(2-pentenyl) 2(dppp)] confirms this isomerization. Possible reaction mechanisms are discussed.