94602-20-7Relevant articles and documents
Robust Buchwald-Hartwig amination enabled by ball-milling
Cao, Qun,Nicholson, William I.,Jones, Andrew C.,Browne, Duncan L.
supporting information, p. 1722 - 1726 (2019/02/20)
An operationally simple mechanochemical method for the Pd catalysed Buchwald-Hartwig amination of arylhalides with secondary amines has been developed using a Pd PEPPSI catalyst system. The system is demonstrated on 30 substrates and applied in the context of a target synthesis. Furthermore, the performance of the reaction under aerobic conditions has been probed under traditional solution and mechanochemical conditions, the observations are discussed herein.
THE REACTIVITY OF SULFUR NUCLEOPHILES TOWARDS ARENEDIAZONIUM TETRAFLUOROBORATES IN APROTIC SOLVENTS: SYNTHESIS OF S-ARYL THIOACETATES
Petrillo, Giovanni,Novi, Marino,Garbarino, Giacomo,Filiberti, Marcos
, p. 4185 - 4188 (2007/10/02)
Various S-aryl thioacetates are prepared in 40-60percent yield by treatment of arenediazonium tetrafluoroborates with commercial potassium thioacetate in DMSO at room temperature.