946164-43-8Relevant articles and documents
Palladium-catalyzed decarboxylative generation and asymmetric allylation of α-imino anions
Qian, Xiaoyan,Ji, Pengfei,He, Chang,Zirimwabagabo, Jean-Olivier,Archibald, Michelle M.,Yeagley, Andrew A.,Chruma, Jason J.
supporting information, p. 5228 - 5231 (2014/12/11)
A palladium-catalyzed asymmetric decarboxylative allylic alkylation of allyl 2,2-diphenylglycinate imines using (S,S)-f-binaphane as a chiral supporting ligand has been developed. This transformation allows for decarboxylative generation and enantioselective allylation of nonenolate α-imino (2-azaallyl anions) to afford α-aryl homoallylic imines.