946826-92-2

Basic information

• Product Name: N-cyano-S-methyl-S-(4-nitrophenyl)sulfilimine
• Synonyms: N-cyano-S-methyl-S-(4-nitrophenyl)sulfilimine
• CAS NO: 946826-92-2
• Molecular Weight: 209.228
• Mol File: 946826-92-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: N-cyano-S-methyl-S-(4-nitrophenyl)sulfilimine(CAS DataBase Reference)
• NIST Chemistry Reference: N-cyano-S-methyl-S-(4-nitrophenyl)sulfilimine(946826-92-2)
• EPA Substance Registry System: N-cyano-S-methyl-S-(4-nitrophenyl)sulfilimine(946826-92-2)

Safety Data

• Hazardous Substances Data: 946826-92-2(Hazardous Substances Data)

Upstream product

• 701-57-5 1-methylthio-4-nitro-benzene 
• 940-12-5 p-nitrophenyl methyl sulfoxide 
• 1849-36-1 para-nitrobenzenethiol 
• 420-04-2 CYANAMID 

Downstream Products

• 946826-73-9 N-[methyl(4-nitrophenyl)(oxo)-λ⁶-sulfanylidene]cyanamide 
• 22133-01-3 S-methyl-S-(4-nitrophenyl)sulfoximine 
• 952022-17-2 N-(trifluoroacetyl)-S-methyl-S-(4-nitrophenyl)sulfoximine 

Relevant articles and documents

Sulfoxide-to-sulfilimine conversions: Use of modified Burgess-type reagents

Sulfoxides can directly be converted into N-cyanosulfilimines using a new Burgess-type reagent. By applying this strategy with a related reagent variant, synthetically valuable NH-sulfoximines have been prepared from sulfoxides via N-protected sulfilimines. The practical three-step reaction sequence is generally high yielding and applicable to a wide range of substrates. The sulfoxide-to-sulfilimine conversion can also be performed under solvent-reduced conditions in a ball mill. Copyright

Synthesis of N-(1H)-tetrazole sulfoximines

N-(1H)-Tetrazole sulfoximines are readily available by addition of sodium azide to the corresponding N-cyano derivatives in the presence of ZnBr 2. The use of these N-(1H)-tetrazoles as intermediates in the synthesis of other N-heterocyclic sulfoximines is demonstrated.