947370-51-6

Basic information

• Product Name: Ru(an-OMe)(Cl)(PPh₃)2
• CAS NO: 947370-51-6
• Molecular Weight: 937.399
• Mol File: 947370-51-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ru(an-OMe)(Cl)(PPh₃)2(CAS DataBase Reference)
• NIST Chemistry Reference: Ru(an-OMe)(Cl)(PPh₃)2(947370-51-6)
• EPA Substance Registry System: Ru(an-OMe)(Cl)(PPh₃)2(947370-51-6)

Safety Data

• Hazardous Substances Data: 947370-51-6(Hazardous Substances Data)

Upstream product

• 30050-39-6 [tris(triphenylphosphine) ruthenium(III) trichloride] 
• 13411-91-1 1-(4-methoxyphenylazo)naphthalen-2-ol 

Relevant articles and documents

Ruthenium(III) mediated C-H activation of azonaphthol: Synthesis, structural characterization and transfer hydrogenation of ketones

Treatment of [RuCl3(PPh3)3] with 1-(arylazo)naphthol ligands in benzene under reflux afford air-stable new organoruthenium(III) complexes with general composition [Ru(an-R)Cl(PPh3)2] (where, R = H, Cl, CH3, OCH3, OC2H5) in fairly good yield. The 1-(arylazo)naphtholate ligands behave as dianionic tridentate C, N, O donors and coordinates to ruthenium through phenolic oxygen, azo nitrogen and ortho carbon generate two five-membered chelate rings. The composition of the complexes have been established by analytical (elemental analysis and magnetic susceptibility measurement) and spectral (FT-IR, UV-Vis, EPR) methods. The complexes are paramagnetic (low-spin, d5) in nature and in dichloromethane solution show intense d-d transitions and ligand-to-metal charge transfer (LMCT) transitions in the visible region. The solution EPR spectrum of complex [Ru(an-CH3)Cl(PPh3)2] (3) in dichloromethane at 77 K shows rhombic distortion around the ruthenium ion with three different 'g' values (gx ≠ gy ≠ gz). The single crystal structure of the complex [Ru(an-OCH3)Cl(PPh3)2] (4) has been characterised by X-ray crystallography, indicates the presence of a distorted octahedral geometry in these complexes. All the complexes exhibit one quasi-reversible oxidative response in the range 0.60-0.79 V (RuIV/RuIII) and two quasi-reversible reductive responses (RuIII/RuII; RuII/RuI) within the range -0.50 to -0.62 V and -0.93 to -0.98 V respectively. The formal potential of all the couples correlate linearly with the Hammett constant of the para substituent in arylazo fragment of the 1-(arylazo)naphtholate ligand. Further, the catalytic efficiency of one of the ruthenium complexes (4) was determined for the transfer hydrogenation of ketones with an excellent yield up to 99% in the presence of isopropanol/KOH.