94741-16-9

Basic information

• Product Name: Silacyclopentane, 1-methyl-1-[(trimethylsilyl)methyl]-
• CAS NO: 94741-16-9
• Molecular Formula: C9H22Si2
• Molecular Weight: 186.445
• Mol File: 94741-16-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Silacyclopentane, 1-methyl-1-[(trimethylsilyl)methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Silacyclopentane, 1-methyl-1-[(trimethylsilyl)methyl]-(94741-16-9)
• EPA Substance Registry System: Silacyclopentane, 1-methyl-1-[(trimethylsilyl)methyl]-(94741-16-9)

Safety Data

• Hazardous Substances Data: 94741-16-9(Hazardous Substances Data)

Upstream product

• 1072-54-4 1,1-dimethyl-1-silacyclopentane 
• 75-77-4 chloro-trimethyl-silane 
• 591-51-5 phenyllithium 
• 109154-39-4 4-(Benzyldimethylsilyl)butyllithium 

Relevant articles and documents

UEBER DIE AUSTAUSCHBARKEIT VON METHYL- UND PHENYLGRUPPEN AM SILICIUM VON SILACYCLOPENTAN BEI DER EINWIRKUNG VON ALKYL- UND ARYLLITHIUMVERBINDUNGEN IN DIETHYLETHER ODER TETRAHYDROFURAN

A degenerate ligand exchange, presumably via an ate-complex intermediate, takes place upon treatment of 1,1-dimethyl- (3) and 1,1-diphenyl-silacyclopentane (17) in THF-d8 with perdeuteriomethyllithium (4-d3) or perdeuteriophenyllithium (15-d5), respective