948595-14-0Relevant articles and documents
Unprecedented use of silver(I) N-heterocyclic carbene complexes for the catalytic preparation of 1,2-bis(boronate) esters
Ramirez, Jesus,Corberan, Rosa,Sanau, Mercedes,Peris, Eduardo,Fernandez, Elena
, p. 3056 - 3058 (2005)
Catalytic diboration of internal and terminal alkenes with Ag(I) N-heterocyclic carbene complexes leads to 1,2-bis(boronate) esters as single intermediates, that can be oxidised towards the corresponding diols. The Royal Society of Chemistry 2005.
Gold(0) nanoparticles for selective catalytic diboration
Ramirez, Jesus,Sanau, Mercedes,Fernandez, Elena
supporting information; experimental part, p. 5194 - 5197 (2009/04/11)
Going with gold: Gold(0) nanoparticles stabilized with the diphosphine ligand binap mediate the catalytic diboration of styrene, resulting in complete formation of the bis(boronate)ester product. The gold(0) catalytic mechanism can involve base-assisted h
Enantioselective preparation of a chiral-at-metal Cp*Ir(NHC) complex and its application in the catalytic diboration of olefins
Corberan, Rosa,Lillo, Vanessa,Mata, Jose A.,Fernandez, Elena,Peris, Eduardo
, p. 4350 - 4353 (2008/10/09)
The reaction of(S,S)-1,3-di(methylbenzyl)imidazolium chloride with [Cp*IrCl2]2 in the presence of NaOAc affords the diastereoselective formation of a Cp*Ir(NHC) complex with a chelating ligand coordinated through the carbene and the