95033-78-6Relevant articles and documents
Catalytic enantioselective oxidative cross-coupling of benzylic ethers with aldehydes
Meng, Zhilin,Sun, Shutao,Yuan, Huiqing,Lou, Hongxiang,Liu, Lei
, p. 543 - 547 (2014/01/23)
The first one-pot enantioselective oxidative coupling of cyclic benzylic ethers with aldehydes has been developed. A variety of benzylic ethers were transformed into the corresponding oxygen heterocycles with high enantioselectivity. Mechanistic experiments were conducted to determine the nature of the reaction intermediates. The application of this strategy to coupling reactions with other nucleophiles besides aldehydes was also explored. In one go: The first one-pot enantioselective oxidative coupling of cyclic benzylic ethers with aldehydes has been developed. A variety of benzylic ethers could be functionalized with this method, and the corresponding oxygen heterocycles were obtained with high enantioselectivity.
Cobalt-Catalyzed Partial Oxidation of Olefins and Ethers Using Molecular Oxygen
Reetz, Manfred T.,Toellner, Karl
, p. 9461 - 9464 (2007/10/02)
Co(acac)3 catalyzes the aerobic oxidation of vinyl aromatic compounds ArCH=CH2 with formation of ArCO2H and ArCHO, and also the aerobic oxidation of cyclic ethers with formation of the corresponding lactones.