950598-44-4

Basic information

• Product Name: C₃₁H₄₅IO₆
• Synonyms: C₃₁H₄₅IO₆
• CAS NO: 950598-44-4
• Molecular Weight: 640.599
• Mol File: 950598-44-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₃₁H₄₅IO₆(CAS DataBase Reference)
• NIST Chemistry Reference: C₃₁H₄₅IO₆(950598-44-4)
• EPA Substance Registry System: C₃₁H₄₅IO₆(950598-44-4)

Safety Data

• Hazardous Substances Data: 950598-44-4(Hazardous Substances Data)

Upstream product

• 698379-54-3 (2E,6E)-8-(4-Methoxy-benzyloxy)-2,6-dimethyl-octa-2,6-dien-1-ol 
• 824-94-2 p-methoxybenzyl chloride 
• 106-24-1 Geraniol 
• 950598-32-0 (2E,5S,5R,7R,9Z,11S,14E)-7,11-epoxy-5,6-(isopropylidenedioxy)-16-(4-methoxybenzyloxy)-2,6,10,14-tetramethylhexadeca-2,9,14-trien-1-ol 
• 950598-31-9 C₄₀H₇₀O₆Si₂ 
• 950598-37-5 C₃₅H₅₆O₇Si 
• 950598-36-4 tert-butyl (3R,4S,5S,7Z,9S,12E)-4,5-epoxy-3-hydroxy-14-(4-methoxybenzyloxy)-4,8,12-trimethyl-9-(triethylsiloxy)tetradeca-7,12-dienoate 
• 950598-30-8 tert-butyl (3S,4S,5S,7Z,9S,12E)-4,5-epoxy-3-hydroxy-14-(4-methoxybenzyloxy)-4,8,12-trimethyl-9-(triethylsiloxy)tetradeca-7,12-dienoate 
• 950598-29-5 (2R,3S,5Z,7S,10E)-2,3-epoxy-12-(4-methoxybenzyloxy)-2,6,10-trimethyl-7-(triethylsiloxy)dodeca-5,10-diene-1-al 
• 950598-28-4 (3Z,5S,8E)-10-(4-methoxybenzyloxy)-4,8-dimethyldeca-3,8-dien-5-olide 
• 950598-27-3 C₂₂H₃₀O₄ 
• 906624-08-6 (2R,3S)-2-Iodomethyl-3-[(E)-5-(4-methoxy-benzyloxy)-3-methyl-pent-3-enyl]-2-methyl-oxirane 
• 906624-11-1 (3S,6E)-8-(4-methoxybenzyloxy)-2,6-dimethylocta-1,6-dien-3-ol 
• 950598-43-3 C₃₁H₄₆O₇ 

Downstream Products

• 950598-45-5 C₃₁H₄₆O₆ 
• 950598-33-1 (2E,6S,7Z,10R,11R,12S,14S)-6,10:14,15-diepoxy-11,12-isopropylidenedioxy-3,7,11,15-tetramethyl-1-(phenylthio)hexadeca-2,7-diene 

Relevant articles and documents

Total synthesis of methyl sarcophytoate, a marine natural biscembranoid

(Chemical Equation Presented) The total synthesis of methyl sarcophytoate (1), a marine natural biscembranoid, has been achieved by the thermal Diels-Alder reaction between the 14-membered dienophile unit, methyl sarcoate (2), and the 14-membered diene unit 64. Methyl sarcoate (2) was prepared using n-BuLi-Bu2Mg-mediated dithiane coupling, Kosugi-Migita-Stille coupling, and Grubbs ring-closing metathesis. The diene unit 64 was prepared using Sharpless asymmetric epoxidation, Grubbs ring-closing metathesis, 6-exo-tet epoxide opening, and n-BuLi-Bu2Mg-mediated Ito-Kodama cyclization. The final Diels-Alder reaction between 2 and 64 proceeded with high site, endo/exo, π-face, and regioselectivities. During this reaction, partial E → Z isomerization at the C4 position was observed.