95110-77-3

Basic information

• Product Name: 2-Octanone, 1-(4-chlorophenyl)-
• CAS NO: 95110-77-3
• Molecular Formula: C14H19ClO
• Molecular Weight: 238.757
• Mol File: 95110-77-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2-Octanone, 1-(4-chlorophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Octanone, 1-(4-chlorophenyl)-(95110-77-3)
• EPA Substance Registry System: 2-Octanone, 1-(4-chlorophenyl)-(95110-77-3)

Safety Data

• Hazardous Substances Data: 95110-77-3(Hazardous Substances Data)

Upstream product

• 104-88-1 4-chlorobenzaldehyde 
• 190065-72-6 1-chloro-4-(oct-1-yn-1-yl)benzene 
• 102116-17-6 2-Benzenesulfinyl-2-chloro-1-(4-chloro-phenyl)-octan-1-ol 
• 70872-75-2 1-chloroheptyl phenyl sulfoxide 
• 95110-73-9 1,2-epoxy-1-(4-chlorophenyl)-2-phenylsulfinyloctane 

Relevant articles and documents

Ring size and nothing else matters: unusual regioselectivity of alkyne hydration by NHC gold(i) complexes

We have investigated the role of ring sizes and substituents in NHC ligands in some (NHC)Au(i) complexes in the hydration of internal alkynes. Despite the fact that using (NHC)Au(i) complexes in the hydration of diarylacetylenes leads to Markovnikov-type products, the precise tuning of ligands allows changing the regioselectivity in arylalkylacetylene hydration to the anti-Markovnikov-type.

α,β-Epoxy Sulfoxides as Useful Intermediates in Organic Synthesis. I. A Novel Synthesis of Dialkyl Ketones and a Synthesis of Aldehydes from Ketones by One Carbon Elongation

Treatment of α,β-epoxy sulfoxides, prepared from 1-chloroalkyl phenyl sulfoxides with ketones or aldehydes, with sodium benzeneselenolate gives dialkyl ketones or aldehydes in good yields under mild conditions.The mechanism of this reaction and an application of this process to a formal total synthesis of dihydrojasmone are described.