951133-52-1

Basic information

• Product Name: (+)-(5S,S(S))-(2E)-[4-(p-tolylsulfinyl)deca-1,3-dien-5-yloxy]triisobutylsilane
• Synonyms: (+)-(5S,S(S))-(2E)-[4-(p-tolylsulfinyl)deca-1,3-dien-5-yloxy]triisobutylsilane
• CAS NO: 951133-52-1
• Molecular Weight: 490.866
• Mol File: 951133-52-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (+)-(5S,S(S))-(2E)-[4-(p-tolylsulfinyl)deca-1,3-dien-5-yloxy]triisobutylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-(5S,S(S))-(2E)-[4-(p-tolylsulfinyl)deca-1,3-dien-5-yloxy]triisobutylsilane(951133-52-1)
• EPA Substance Registry System: (+)-(5S,S(S))-(2E)-[4-(p-tolylsulfinyl)deca-1,3-dien-5-yloxy]triisobutylsilane(951133-52-1)

Safety Data

• Hazardous Substances Data: 951133-52-1(Hazardous Substances Data)

Upstream product

• 951133-73-6 (R)-(1,3-Butadienyl)-p-tolyl-sulfoxid 
• 66-25-1 hexanal 
• 951133-45-2 (+)-(5S,S(S))-(4E)-4-(p-tolylsulfinyl)deca-1,3-dien-5-ol 
• 13154-25-1 triiso-butylchlorosilane 

Downstream Products

• 951133-77-0 (-)-(5S)-(4E)-4-(p-tolylsulfonyl)deca-1,3-dien-5-ol 
• 1092556-39-2 C₂₉H₅₀O₄SSi 
• 1092556-33-6 C₂₉H₅₀O₃SSi 
• 951133-79-2 (2R,5S)-5-pentyl-4-(p-tolylsulfonyl)-2,5-dihydrofuran-2-methanol 
• 951133-63-4 (2S,5S)-5-pentyl-4-(p-tolylsulfonyl)-2,5-dihydrofuran-2-methanol 
• 951133-94-1 (+)-(2S,3S,5R)-3-phenylcarbonyloxy-5-hydroxymethyl-2-pentyl-tetrahydrofuran 
• 128707-15-3 (2R,4S,5S)-tetrahydro-4-hydroxy-5-pentyl-2-furfuraldehyde (benzoate) 
• 951133-93-0 (+)-(2S,3S,5R)-5-(tert-butyldimethylsilyloxymethyl)-3-phenylcarbonyloxy-2-pentyl-tetrahydrofuran 
• 951133-90-7 (-)-(2S,3S,4S,5S)-2-(tert-butyldimethylsilyloxymethyl)-3,4-epoxy-5-pentyl-4-(p-tolylsulfonyl)tetrahydrofuran 
• 951133-89-4 (-)-(2R,5S)-2-(tert-butyldimethylsilyloxymethyl)-5-pentyl-4-(p-tolylsulfonyl)-2,5-dihydrofuran 
• 1092556-09-6 (-)-(2S,5S)-2-(tert-butyldimethylsilyloxymethyl)-5-pentyl-4-(p-tolylsulfonyl)-2,5-dihydrofuran 

Relevant articles and documents

Highly diastereoselective Katsuki-Jacobsen oxidation-epoxidation of α-silyloxy sulfinyl dienes: Synthetic applications

(Chemical Equation Presented) Katsuki-Jacobsen oxidation-epoxidation of acyclic α-silyloxy sulfinyl dienes, followed by acid-promoted cyclization, leads to 2,5-trans-sulfonyl dihydrofurans with good selectivities. As an application, the formal syntheses of (6S,7S,9R,10R)- and (6S,7S,9S,10S)-6,9- epoxynonadec-18-ene-7,10-diols is reported.