95120-27-7Relevant articles and documents
Conversion of l-rhamnose into ten of the sixteen 1- and 6-deoxyketohexoses in water with three reagents: d-tagatose-3-epimerase equilibrates C3 epimers of deoxyketoses
Gullapalli, Pushpakiran,Yoshihara, Akihide,Morimoto, Kenji,Rao, Devendar,Akimitsu, Kazuya,Jenkinson, Sarah F.,Fleet, George W.J.,Izumori, Ken
supporting information; experimental part, p. 895 - 898 (2010/05/03)
The efficient isomerization of l-rhamnose [the only cheaply available deoxy hexose] to 1-deoxy-l-psicose, 1-deoxy-d-psicose, 1-deoxy-l-fructose, 1-deoxy-d-fructose, 1-deoxy-l-tagatose, 6-deoxy-l-psicose, 6-deoxy-d-psicose, 6-deoxy-l-fructose, 6-deoxy-d-fructose, and 6-deoxy-l-tagatose is described. The conversion of rhamnose to ten of the sixteen 1- and 6-deoxyketohexoses is accomplished in water in three steps. The range of substrates for d-tagatose-3-epimerase (DTE) is extended to 1- and 6-deoxyketoses. An authentic sample of 6-deoxy-d-psicose is prepared from d-psicose.
C-nucleoside studies. I. Synthesis of (2,3,5-tri-O-benzyl-alpha(and beta)-D-ribofuranosyl)ethyne.
Buchanan,Edgar,Power
, p. 1943 - 1949 (2007/10/10)
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