95149-16-9

Basic information

• Product Name: tris-(3-methoxy-phenyl)-bismuthane
• Synonyms: tris-(3-methoxy-phenyl)-bismuthane
• CAS NO: 95149-16-9
• Molecular Weight: 530.376
• Mol File: 95149-16-9.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: tris-(3-methoxy-phenyl)-bismuthane(CAS DataBase Reference)
• NIST Chemistry Reference: tris-(3-methoxy-phenyl)-bismuthane(95149-16-9)
• EPA Substance Registry System: tris-(3-methoxy-phenyl)-bismuthane(95149-16-9)

Safety Data

• Hazardous Substances Data: 95149-16-9(Hazardous Substances Data)

Upstream product

• 36282-40-3 (3-methoxyphenyl)magnesium bromide 
• 2398-37-0 3-methoxyphenyl bromide 
• 7787-60-2 bismuth(III) chloride 

Downstream Products

• 153000-44-3 3-(3-methoxyphenyl)-4H-chromen-4-one 
• 1017073-41-4 C₁₇H₁₄O₃ 
• 71897-08-0 2-(3-methoxyphenyl)quinoxaline 
• 1010706-02-1 1-(3-methoxyphenoxy)-3,5-dimethylbenzene 
• 107624-96-4 3-methoxy-4'-nitro-1,1'-biphenyl 
• 171046-94-9 (S)-3-(3-methoxyphenyl)cyclopentanone 
• 81443-45-0 (3'-methoxybiphenyl-4-yl)methanol 

Relevant articles and documents

Palladium-Catalyzed Cross-Coupling of Arenediazonium Salts with Organoindium or Organobismuth Reagents

Arylindium and isolated triarylbismuth compounds generated in situ react as nucleophiles with arenediazonium salts in palladium-catalyzed cross-coupling reactions to give substituted biphenyls.

Synthesis of highly functionalized diaryl ethers by copper-mediated O-arylation of phenols using trivalent arylbismuth reagents

Highly functionalized diaryl ethers were prepared by copper(II) acetate mediated O-arylation reaction of phenols using trivalent organobismuthanes. The reaction is performed under simple conditions and tolerates a wide diversity of functional groups on the phenol and on the organobismuth reagent. Substoichiometric amounts of catalyst can be used by performing the reaction under an oxygen atmosphere. The N-arylation of pyridones is also reported. Highly functionalized diaryl ethers were prepared by a copper(II) acetate mediated O-arylation reaction of phenols using trivalent organobismuthanes (see scheme). The reaction is performed under simple conditions and tolerates a wide diversity of functional groups on the phenol and on the organobismuth reagent. Substoichiometric amounts of catalyst can be used by performing the reaction under an oxygen atmosphere. The N-arylation of pyridones is also reported. FG=functional group.

Cyclic ureas as ortho directing substituents

Six-membered cyclic ureas are shown to have a weak ortho directing ability when linked through nitrogen to benzene and pyridine rings.