95199-21-6Relevant articles and documents
Redox-Mediated Decarboxylative Photo-Phenylselenenylation of N-Acyloxyphthalimides
Okada, Keiji,Okubo, Katsura,Morita, Naoto,Oda, Masaji
, p. 2021 - 2024 (2007/10/02)
Decarboxylative phenylselenenylation of N-acyloxyphthalimides by visible light irradiation in aqueous solvents using catalytic amount of Ru(bpy)3Cl2 as a sensitizer in the presence of one equivalent of BNAH and 0.5 equivalent of diphenyl diselenide effici
THE INVENTION OF NEW RADICAL CHAIN REACTIONS. PART XIII. HIGH YIELDING DECARBOXYLATIVE CHALCOGENATION OF ALIPHATIC AND ALICYCLIC ACIDS
Barton, Derek H.R.,Bridon, Dominique,Zard, Samir Z.
, p. 449 - 462 (2007/10/02)
Irradiation with a tungsten lamp of mixed anhydrides (e.g. 8) derived from aliphatic or alicyclic carboxylic acids and N-hydroxy-2-pyridine thione 3 in the presence of a disulphide, diselenide or ditelluride gives the corresponding chalcogenide (e.g. 9, 10, or 11) in high yield.The process involves a radical decarboxylation followed by SH2 reaction of the intermediate carbon radical on the dichalcogenide.