95199-58-9Relevant articles and documents
FACILE ROUTE TO 1-PHOSPHORYL- AND 1-SULFONYL-1,3-DIENES VIA PALLADIUM-CATALYZED ELIMINATION OF ALLYLIC ACETATES
Akermark, Bjoern,Nystroem, Jan-E.,Rein, Tobias,Baeckvall, Jan-E.,Helquist, Paul,Aslanian, Robert
, p. 5719 - 5722 (2007/10/02)
The palladium(II)-catalyzed chloroacetoxylation of 1,3-dienes is employed to prepare 1-chloro-4-acetoxy-2-alkenes which are then transformed into 1-phosphoryl- or 1-sulfonyl-4-acetoxy-2-alkenes respectively.Elimination of acetate is promoted by palladium(