95527-15-4Relevant articles and documents
Aluminum-Catalyzed Selective Hydroboration of Alkenes and Alkynylsilanes
Li, Feng,Bai, Xu,Cai, Yuan,Li, Han,Zhang, Shuo-Qing,Liu, Feng-Hua,Hong, Xin,Xu, Youjun,Shi, Shi-Liang
supporting information, p. 1703 - 1708 (2019/09/04)
An efficient aluminum-catalyzed selective hydroboration of alkenes and alkynylsilanes is reported. A wide variety of alkenes and alkynylsilanes bearing various functional groups and heterocyclic substituents were converted to boronic ester products in goo
A facile stereoselective synthesis of (E)-α-silylvinylstannanes via hydromagnesiation of alkynylsilanes
Cai, Mingzhong,Hao, Wenyan,Zhao, Hong,Xia, Jun
, p. 3593 - 3597 (2007/10/03)
(E)-α-Silylvinylstannanes have been synthesized by the hydromagnesiation reaction of alkynylsilanes, followed by the reaction with trialkylstannyl chlorides. (E)-α-Silylvinylstannanes can undergo the cross-coupling reaction with aryl iodides in the presence of a catalytic amounts of Pd(PPh3)4 and CuI to afford (Z)-1,2-disubstituted vinylsilanes in good yields.
Stereo- and Regioselective Generation of Alkenylzinc Reagents via Titanium-Catalyzed Hydrozincation of Internal Acetylenes
Gao, Yuan,Harada, Kousuke,Hata, Takeshi,Urabe, Hirokazu,Sato, Fumie
, p. 290 - 291 (2007/10/02)
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