95583-32-7

Basic information

• Product Name: (CO)5WH₂NC₆H₄NH₂W(CO)5
• CAS NO: 95583-32-7
• Molecular Weight: 755.947
• Mol File: 95583-32-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (CO)5WH₂NC₆H₄NH₂W(CO)5(CAS DataBase Reference)
• NIST Chemistry Reference: (CO)5WH₂NC₆H₄NH₂W(CO)5(95583-32-7)
• EPA Substance Registry System: (CO)5WH₂NC₆H₄NH₂W(CO)5(95583-32-7)

Safety Data

• Hazardous Substances Data: 95583-32-7(Hazardous Substances Data)

Upstream product

• 36477-75-5 tungsten pentacarbonyl tetrahydrofuran 
• 106-50-3 1,4-phenylenediamine 
• 4377-73-5 2,5-cyclohexadiene-1,4-diimine 

Relevant articles and documents

REAKTIONEN AN KOMPLEXGEBUNDENEN LIGANDED. XXXVI. SYNTHESE UND OXIDATIONSVERHALTEN VON M(CO)5-KOMPLEXEN (M = Cr, Mo, W) MIT AMIN- UND BENZOCHINONDIIMIN-LIGANDEN

The oxidation of yellow Cr(CO)5NH2R complexes (NH2R = aniline, m-toluidine, 3,5-xylidine, m-anisidine) with Pbac4 gives deep blue to deep purple coloured compounds, which have been identified as the respective complexes.Oxidation of the p-phenylenediamine complex yields , which is also deep blue.The binuclear blue complex 2HN=C6H4=NC6H5> is obtained by treating Cr(CO)5THF with the free ligand in THF/hexane; it dissociates rapidly in acetone to form and Cr(CO)5.Analogous Mo(CO)5 and W(CO)5 complexes could not be obtained.The oxidation of W(CO)5(m-anisidine)> by I2 yields 2.All the compounds were characterized by spectroscopic methods as well as by elemental analysis.