95687-88-0Relevant articles and documents
A SIMPLE APPROACH TO NORTROPANE AND NORTROP-6-ENE DERIVATES
Bathgate, Antoinette,Malpass, John R.
, p. 5937 - 5940 (2007/10/02)
Intramolecular cyclisation of trans-1-(benzylamino)-4-chlorocycloheptane and hept-2-ene gives the corresponding 8-azabicyclo(3.2.1)octane (nortropane) and -oct-6-ene (nortrop-6-ene) derivatives respectively.Under appropriate conditions, cyclohept-1,3-diene is converted into nortropane in 75percent overall yield.
A NEW SYNTHETIC ROUTE TO TROPANE ALKALOIDS. PSEUDOTROPINE AND TROPACOCAINE
Iida, Hideo,Watanabe, Yohya,Kibayashi, Chihiro
, p. 5091 - 5094 (2007/10/02)
Pseudotropine and tropacocaine have been synthesized by a facile route involving the nitroso cycloaddition followed by internal SN2 displacement.