958028-58-5Relevant articles and documents
COORDINATION COMPLEX AND ELECTRONIC DEVICE COMPRISING THE SAME
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Page/Page column 42, (2019/07/13)
The present invention relates to an electronic device comprising a hole injection layer and/or a hole transport layer and/or a hole generating layer, wherein at least one of the hole injection layer, the hole transport layer and the hole generating layer
LITHIUM SALTS OF PENTAFLUOROPHENYLAMIDE ANIONS, PREPARATION THEREOF AND USE THEREOF
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Page/Page column 8, (2012/10/08)
The present invention provides new lithium salts comprising pentafluorophenylamide anions following the general formula Li+[N(SO2—R)(C6F5)]?, which are optionally present as solvent-free complexes. R is hereby selected from fluorine, linear or branched acyclic or cyclic alkyl groups with 1 to 20 carbon atoms which are not fluorinated, partially fluorinated or fully fluorinated; or not fluorinated, partially fluorinated or fully fluorinated aryl or benzyl groups with 1 to 20 carbon atoms. The lithium salts according to the present invention are produced by reacting the corresponding NH acid of the pentafluorophenylamide with one equivalent of lithium bis(trimethylsilyl)amide or lithium organyl, wherein the reaction is carried out advantageously in the presence of apolar aprotic solvents. In this way, lithium salts in the form of solvent-free complexes are obtained. These solvent-free lithium complexes are thermally, electrochemically and against oxidation stable and comprise a high ionic conductivity. The lithium salts according to the present invention are suitable to be used as ion-conducting materials, electrically conductive materials, dyes and in chemical catalysis. They are preferably used as ion-conducting electrolytes in lithium ion accumulators.
Three novel anions based on pentafluorophenyl amine combined with two new synthetic strategies for the synthesis of highly lipophilic ionic liquids
Linder, Thomas,Sundermeyer, Joerg
supporting information; experimental part, p. 2914 - 2916 (2009/12/01)
The three new fluorinated anions BPFPA, PFTFSI, and PFNFSI for highly hydrophobic, hydrolytically stable ionic liquids are introduced, together with a strategy allowing a combinatorial approach for the synthesis of imidazolium and phosphonium based ionic