958640-54-5

Basic information

• Product Name: 4-(4-trimethylsiloxyphenyl)-2-methyl-2-butanol
• CAS NO: 958640-54-5
• Molecular Weight: 252.429
• Mol File: 958640-54-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-(4-trimethylsiloxyphenyl)-2-methyl-2-butanol(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(4-trimethylsiloxyphenyl)-2-methyl-2-butanol(958640-54-5)
• EPA Substance Registry System: 4-(4-trimethylsiloxyphenyl)-2-methyl-2-butanol(958640-54-5)

Safety Data

• Hazardous Substances Data: 958640-54-5(Hazardous Substances Data)

Upstream product

• 5471-51-2 4-(4-hydroxyphenyl)-2-oxobutane 
• 522617-84-1 4-(4-trimethylsilyloxyphenyl)butan-2-one 
• 917-64-6 methyl magnesium iodide 

Downstream Products

• 958640-55-6 4-(4-trimethylsiloxyphenyl)-2-methyl-2-trimethylsiloxybutane 
• 958640-41-0 4-(4-hydroxyphenyl)-2-methyl-2-trimethylsiloxybutane 

Relevant articles and documents

InCl3-catalyzed cross-coupling of alkyl trimethylsilyl ethers and allylsilanes via an in situ derived combined lewis acid of InCl3 and Me3SiI

(Chemical Equation Presented) Direct Csp3-Csp3 coupling of various aliphatic trimethylsilyl ethers and allylsilanes is effectively catalyzed by InCl3 and I2. The transformation is thought to involve an in situ-derived combined Lewis acid of InCl3 and Me3SiI. The reaction can be used for the construction of quaternary-quaternary and quaternary-tertiary carbon-carbon bonds. This system enabled a highly chemoselective coupling to be conducted with a trimethylsilyl ether including an aryl halide moiety. Furthermore, couplings were possible using an alkynyltri-methylsilane and a trimethylsilyl ketene acetal.