959428-53-6

Basic information

• Product Name: [(P(C₆H₄F)3)2PdCl(C₆H₂(CHNCH₂C₆H₅)2C(CH₃)3)]
• CAS NO: 959428-53-6
• Molecular Weight: 1141.91
• Mol File: 959428-53-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(P(C₆H₄F)3)2PdCl(C₆H₂(CHNCH₂C₆H₅)2C(CH₃)3)](CAS DataBase Reference)
• NIST Chemistry Reference: [(P(C₆H₄F)3)2PdCl(C₆H₂(CHNCH₂C₆H₅)2C(CH₃)3)](959428-53-6)
• EPA Substance Registry System: [(P(C₆H₄F)3)2PdCl(C₆H₂(CHNCH₂C₆H₅)2C(CH₃)3)](959428-53-6)

Safety Data

• Hazardous Substances Data: 959428-53-6(Hazardous Substances Data)

Upstream product

• 866343-75-1 [4-tert-butyl-2,6-bis(N-benzylimino)phenyl]chloropalladium 
• 23039-94-3 tris(3-fluorophenyl)phosphine 

Relevant articles and documents

Pd pincer complex as a probe to index the coordination ability of various ligands

An NCN pincer palladium complex was developed as a probe molecule to index the coordination ability of various monodentate ligands. Coordination constants of 27 monodentate ligands (L) with a pincer palladium complex to form complexes of the type ArPd(L)2Cl were determined by 1H NMR spectroscopy. This allowed the coordination ability of a wide variety of ligands, including P-coordinating ligands (phosphane, phosphite), as well as As-coordinating AsPh3, and N-coordinating pyridine, to be indexed. The differential between the highest/lowest coordination constants was 10 12. The relative coordination ability is described in a logarithmic manner, log(Keq(L)/Keq(PPh3)), with respect to the value of PPh3 to exhibit high linearity in the Hammett plot. Wiley-VCH Verlag GmbH & Co. KGaA, 2007.