959925-23-6

Basic information

• Product Name: (CH₃)3CC₆H₄C(CH₂)OB(N(Si(CH₃)3)2)2
• Synonyms: (CH₃)3CC₆H₄C(CH₂)OB(N(Si(CH₃)3)2)2
• CAS NO: 959925-23-6
• Molecular Weight: 506.835
• Mol File: 959925-23-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (CH₃)3CC₆H₄C(CH₂)OB(N(Si(CH₃)3)2)2(CAS DataBase Reference)
• NIST Chemistry Reference: (CH₃)3CC₆H₄C(CH₂)OB(N(Si(CH₃)3)2)2(959925-23-6)
• EPA Substance Registry System: (CH₃)3CC₆H₄C(CH₂)OB(N(Si(CH₃)3)2)2(959925-23-6)

Safety Data

• Hazardous Substances Data: 959925-23-6(Hazardous Substances Data)

Upstream product

• 943-27-1 4'-t-butylacetophenone 
• 6591-25-9 Bis-(-bis-trimethylsilylamino)-chlor-boran 

Relevant articles and documents

Synthesis and structural characterization of the bis(diisopropylamino)boron enolate of tert-butyl methyl ketone

Lithium, sodium, and potassium enolates reacted with bisaminoboron halides to give bisaminoboron enolates 1a-5c. Specifically, the potassium enolate of tert-butyl methyl ketone reacted with bis-(diisopropylamino)boron chloride in THF at room temperature within 1h to give the bis(diisopropylamino)-boron enolate of tert-butyl methyl ketone (3b) in 61-84% isolated yields. Under similar conditions, the reactivity is highly dependent on the metal employed to generate enolates (K > Na > Li) as well as the nitrogen substituents in the bisaminoboron halides (iPr > Et > TMS). This latter observation is a compromise between the boron-nitrogen resonance and the steric effect. The structural information of enolate 3b was studied in detail. Unlike the aggregated alkali-metal enolates, this boron enolate exists exclusively as a monomer in both the solid and solution states, as identified by X-ray and diffusion-ordered NMR.