96013-81-9

Basic information

• Product Name: Benzenemethanol, a-butyl-4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-
• CAS NO: 96013-81-9
• Molecular Formula: C17H30O2Si
• Molecular Weight: 294.51
• Mol File: 96013-81-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-butyl-4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-butyl-4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-(96013-81-9)
• EPA Substance Registry System: Benzenemethanol, a-butyl-4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-(96013-81-9)

Safety Data

• Hazardous Substances Data: 96013-81-9(Hazardous Substances Data)

Upstream product

• 96013-70-6 1-(tert-Butyl-dimethyl-silanyloxy)-4-[1-(tert-butyl-dimethyl-silanyloxy)-pentyl]-benzene 
• 123-08-0 4-hydroxy-benzaldehyde 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Downstream Products

• 2589-71-1 4'-hydroxyvalerophenone 

Relevant articles and documents

Rhodium-Catalyzed Deoxygenation and Borylation of Ketones: A Combined Experimental and Theoretical Investigation

The rhodium-catalyzed deoxygenation and borylation of ketones with B2pin2 have been developed, leading to efficient formation of alkenes, vinylboronates, and vinyldiboronates. These reactions feature mild reaction conditions, a broad substrate scope, and excellent functional-group compatibility. Mechanistic studies support that the ketones initially undergo a Rh-catalyzed deoxygenation to give alkenes via boron enolate intermediates, and the subsequent Rh-catalyzed dehydrogenative borylation of alkenes leads to the formation of vinylboronates and diboration products, which is also supported by density functional theory calculations.