96185-91-0

Basic information

• Product Name: MONO-METHYL CIS-5-NORBORNENE-ENDO-2,3-DICARBOXYLATE
• Synonyms: MONO-METHYL CIS-5-NORBORNENE-ENDO-2,3-DICARBOXYLATE;mono-Methyl cis-5-norbornene-endo-2,3-dicarboxylate 95%;mono-methyl cis-5-norbornene-endo-2,3-dicarboxyla
• CAS NO: 96185-91-0
• Molecular Formula: C₁₀H₁₂O₄
• Molecular Weight: 196.2
• EINECS: 1312995-182-4
• Product Categories: Norbornene Derivatives;Alicyclic/Etch-Resistant Monomers;Lithography Monomers;Self Assembly&Contact Printing
• Mol File: 96185-91-0.mol
• Article Data: 5

Chemical Properties

• Melting Point: 103-105 °C(lit.)
• Boiling Point: 327.6°Cat760mmHg
• Flash Point: 130.4°C
• Appearance: /
• Density: 1.322g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.546
• CAS DataBase Reference: MONO-METHYL CIS-5-NORBORNENE-ENDO-2,3-DICARBOXYLATE(CAS DataBase Reference)
• NIST Chemistry Reference: MONO-METHYL CIS-5-NORBORNENE-ENDO-2,3-DICARBOXYLATE(96185-91-0)
• EPA Substance Registry System: MONO-METHYL CIS-5-NORBORNENE-ENDO-2,3-DICARBOXYLATE(96185-91-0)

Safety Data

• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38
• Safety Statements: 26-37/39
• WGK Germany: 3
• Hazardous Substances Data: 96185-91-0(Hazardous Substances Data)

Usage

Description

MONO-METHYL CIS-5-NORBORNENE-ENDO-2,3-DICARBOXYLATE is a colorless liquid chemical compound with the molecular formula C11H14O4. It is known for its high thermal stability and excellent mechanical properties, making it a valuable ingredient in the manufacturing of advanced materials.

Uses

Used in Polymer and Plastics Production:
MONO-METHYL CIS-5-NORBORNENE-ENDO-2,3-DICARBOXYLATE is used as a monomer in the synthesis of specialty polymers and resins. Its high thermal stability and excellent mechanical properties contribute to the production of various polymers and plastics with enhanced performance characteristics.
Used in Adhesives and Coatings Industry:
MONO-METHYL CIS-5-NORBORNENE-ENDO-2,3-DICARBOXYLATE is used as a crosslinking agent in the production of adhesives and coatings. Its ability to form strong chemical bonds helps improve the durability and performance of these products, making them suitable for various industrial and commercial applications.

InChI:InChI=1/C10H12O4/c1-14-10(13)8-6-3-2-5(4-6)7(8)9(11)12/h2-3,5-8H,4H2,1H3,(H,11,12)/t5-,6+,7-,8+/m1/s1

Upstream product

• 67-56-1 methanol 
• 2746-19-2 (1R,2R,6S,7S)-4-oxa-tricyclo[5.2.1.0^2,6]dec-8-ene-3,5-dione 
• 542-92-7 cyclopenta-1,3-diene 
• 3014-58-2 dimethyl (exo,endo)-bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate 
• 624-49-7 dimethylfumarate 
• 3014-58-2 dimethyl 5-cis-norbornene-2,3-dicarboxylate 

Downstream Products

• 39589-98-5 endo-bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic dimethyl ester 
• 121843-92-3 N-cyclohexyl-exo-norbornene-5,6-dicarboximide 
• 64550-47-6 (3aS*,4R*,7S*,7aR*)-3a,4,7,7a-tetrahydro-4,7-methanoisobenzofuran-1(3H)-one 

Relevant articles and documents

Enantioselective acyl-transfer catalysis by fluoride ions

The asymmetric nucleophilic catalysis by fluoride ions at a carbon-based electrophile has been demonstrated for the first time. Using a library of ad hoc designed bifunctional phase-transfer catalysts in which both the anion and the cation are directly involved in the reaction, the desymmetrisation of meso-succinic and -glutaric anhydrides is possible.19F NMR spectroscopic studies support the intermediacy of an acyl fluoride intermediate.

New exo/endo selectivity observed in monohydrolysis of dialkyl bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylates

New monohydrolysis reactions of several exo or endo dimethyl or diethyl bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylates showed higher selectivity toward monohydrolyses of exo-carboalkoxy groups, although the reaction centers are located away from the norborne

Enzymatic optical resolution of norbornanecarboxylic esters using Pig Liver Esterase

The hydrolysis of a series of norbornane-type carboxylic esters catalyzed by pig liver esterase (PLE) has been investigated.It was found that an exo-ester function (syn to the C7 methylene group) is hydrolyzed with high preference.Enantioselective hydrolysis can be accomplished when a vicinal carbonyl-containing function (ester, formyl, acetyl) is present in a trans position with respect to the exo ester.The regiospecifity of the enzymatic hydrolysis has been used for the separation of exo/endo mixtures of the cycloadducts derived from cyclopentadiene and alkene esters.The regiospecifity and enantioselectivity of the enzymatic hydrolysis of norbornane-type esters were analyzed in terms of Tamm's substrate model and also by Griengl's method.